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深冷时间对低碳高合金马氏体钢组织性能的影响

何金1,杨 彬1,王迎春1,2 *(),迟宏宵3,周 健3, 程兴旺1,2   

  1. (1. 北京理工大学 材料学院,北京100081;2. 冲击环境材料技术国家级重点实验室,北京100081; 3. 钢铁研究总院特殊钢研究院,北京 100081)
  • 收稿日期:2024-07-02 修回日期:2025-02-24
  • 通讯作者: *通信作者邮箱:wangyc@bit.edu.cn
  • 基金资助:
    国家科技重大专项资助((J2019-VI-0019-0134))

Effect of Cryogenic Treatment Time on Microstructure and Mechanical properties of a low-carbon high-alloy martensite steel

HE Jin1, YANG Bin1, WANG Ying-chun1,2*(), CHI Hong-xiao3,ZHOU Jian3, CHENG Xing-wang1,2   

  1. (1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China; 2. National Key Laboratory of Science and Technology on Materials Under Shock and Impact, Beijing 100081, China; 3. Institute for Special Steels, Central Iron and Steel Research Institute, Beijing 100081, China)
  • Received:2024-07-02 Revised:2025-02-24

摘要: 研究了深冷时间对经淬火、深冷和回火处理后的低碳Co-Cr-Mo-Ni-W高合金钢组织和力学性能影响,结果表明,不同工艺处理后的组织均由回火马氏体、残余奥氏体和纳米碳化物组成;在2~6h范围内,随着深冷时间延长,由于回火马氏体板条细化,残余奥氏体含量降低,位错密度提高,纳米级碳化物数量增加且分布均匀化,强度显著提高,塑性逐渐降低;深冷时间超过6h后,残余奥氏体含量继续减小,位错密度增加,纳米碳化物尺寸长大,数量减少,强度和塑性均变化不大。试验条件下,深冷时间为6h时,获得了超高强度和良好的强塑性匹配,屈服和抗拉强度分别为 1685MPa和1946MPa,延伸率为14.5%。

关键词: 低碳高合金钢, 深冷处理, 纳米碳化物, 残余奥氏体, 力学性能

Abstract: Microstructure and mechanical properties of a low-carbon Co-Cr-Mo-Ni-W high-alloy martensite steel after quenching, cryogenic treatment for different time and tempering were investigated. The results show that the microstructure under different conditions contains the complex phases with tempered martensite, retained austenite and nano-carbides. With increasing cryogenic time from 2 to 6h, the strength significantly improves but ductility reduces due to the combination of the refinement of tempered martensite lath, the decrease of retained austenite volume fraction, the increase of dislocation density and the number increase of nano-carbides with more uniformly distribution. When cryogenic time over 6 h, both strength and ductility change slightly because retained austenite volume fraction decreases, dislocation density increases and nano-carbide sizes coarsen with number decreasing. An excellent combination of strength and ductility, having a yield strength of 1685 MPa, an ultimate strength of 1946 MPa, an elongation of 14.5%, is achieved for the steel after quenching, cryogenic treatment for 6h and tempering.

Key words: low-carbon high-alloy steel, cryogenic treatment, nano-carbide, retained austenite, mechanical properties