高氯酸铵/铝粉—复合改性双基推进剂燃速与热分解的相关性研究

兵工学报 ›› 2010, Vol. 31 ›› Issue (10): 1351-1356.

高氯酸铵/铝粉—复合改性双基推进剂燃速与热分解的相关性研究

李吉祯, 付小龙, 刘小刚, 樊学忠, 刘子如, 张腊莹

（西安近代化学研究所，陕西西安 710065）

收稿日期:2009-08-25 修回日期:2009-08-25 上线日期:2014-05-04
通讯作者: 李吉祯 E-mail:jizhenli@126.com
作者简介:李吉祯（1980—），男，高级工程师，博士

Correlation Between Burning Rate and Thermal Decomposition of AP/Al-CMDB Propellants

LI Ji-zhen, FU Xiao-long, LIU Xiao-gang, FAN Xue-zhong, LIU Zi-ru, ZHANG La-ying

(Xi'an Modern Chemistry Research Institute, Xi'an 710065, Shaanxi, China)

Received:2009-08-25 Revised:2009-08-25 Online:2014-05-04
Contact: LI Ji-zhen E-mail:jizhenli@126.com

摘要/Abstract

摘要： 利用高压差示扫描量热（PDSC）法研究了高氯酸铵/铝粉—复合改性双基(AP/Al-CMDB)推进剂在1.0~13.0 MPa压强范围内的燃速与高压热分解特性的相关性。研究结果表明，AP/Al-CMDB推进剂在1.0~13.0 MPa压强范围内的燃速与高压热分解的相关性模型中需将压强p和放热速度ΔH_d/Δθ两个影响因子对推进剂燃速的影响程度分开独立考虑，该相关性符合模型关系式u=k_up^a［ΔH_d/Δθ］^b，利用该相关性模型所得的燃速计算值与实测值之间的误差低于2.50%.

关键词: 分析化学, 高氯酸铵/铝粉—复合改性双基推进剂, 燃烧性能, 热分解, 相关性

Abstract: The correlation between burning rate and thermal decomposition of AP/Al-CMDB propellants in the pressure range of 1.0~13.0 MPa were studied by a high pressure differential scanning calorimetry (PDSC). The results show that the factors of pressure p and exothermic rate ΔH_d/Δθ must be analyzed respectively in the model of the correlation between burning rate and thermal decomposition of AP/Al-CMDB propellants in the pressure range of 1.0~13.0 MPa, where the formula of the correlation model is u=k_uP^a［ΔHd/Δθ］^b. The calculated results show that there is an error of lower than 2.50% between the theoretical burning rates and the experimental values.

Key words: analytical chemistry, AP/Al-CMDB propellant, combustion characteristic, thermal decomposition, correlation

中图分类号:

TJ55
O64

李吉祯, 付小龙, 刘小刚, 樊学忠, 刘子如, 张腊莹. 高氯酸铵/铝粉—复合改性双基推进剂燃速与热分解的相关性研究[J]. 兵工学报, 2010, 31(10): 1351-1356.

LI Ji-zhen, FU Xiao-long, LIU Xiao-gang, FAN Xue-zhong, LIU Zi-ru, ZHANG La-ying. Correlation Between Burning Rate and Thermal Decomposition of AP/Al-CMDB Propellants[J]. Acta Armamentarii, 2010, 31(10): 1351-1356.

参考文献

［1］刘艳. 热分析技术在研究含能材料热分解化学中的新应用［D］.西安：西安近代化学研究所, 2003.
LIU Yan. New applications of thermal analysis technique on investigation of energetic material decomposition chemistry［D］. Xi'an: Xi'an Modern Chemistry Research Institute, 2003.(in Chinese)
［2］刘子如, 刘艳, 赵凤起, 等. RDX-CMDB推进剂的催化热分解及其与燃速的相关性［J］. 含能材料, 2007, 15(4): 301-304.
LIU Zi-ru, LIU Yan, ZHAO Feng-qi, et al. Catalytic decomposition of RDX-CMDB and its correlation with burning rate［J］. Chinese Journal of Energetic Materials, 2007, 15(4): 301-304.(in Chinese)
［3］任晓宁, 李笑江, 刘子如, 等. RDX-CMDB推进剂的高压热分解与燃烧性能的相关性［J］. 含能材料, 2007, 15(1): 47-49.
REN Xiao-ning, LI Xiao-jiang, LIU Zi-ru, et al. Correlation between thermal decomposition at high pressure and combustion property for RDX-CMDB propellants［J］. Chinese Journal of Energetic Materials, 2007, 15(1): 47-49.(in Chinese)
［4］刘子如. 含能材料热分析［M］. 北京：国防工业出版社, 2008：293-295.
LIU Zi-ru. Thermal analyses for energetic materials［M］. Beijing: National Defense Industry Press, 2008: 293-295.(in Chinese)
［5］ Lengelle G. Thermal degradation kinetics and surface pyrolysis of viny polymers［J］. AIAA Journal, 1970, 8( 11): 1989-1996.
［6］ Brill T B, Arisawa H, Brush P J, et al. Surface chemistry of burning explosives and propellants［J］. Journal of Physical and Chemistry, 1995, 99: 1384-1392.
［7］ Chen J K, Brill T B. Termal decomposition of energetic materials 54. kinetics and near-surface products of azide polymers AMMO, BAMO, and GAP in simulated combustion［J］. Combustion and Flame, 1991, 87: 157-168.
［8］ Pliukhin B I. On the stationary theory for heat balance of powder and explosive condensed phase［C］∥The 8th Symposium on Combustion, Williams and Wilkins. Baltimore: Williams and Wilkins, 1961:734-785.
［9］ Kubota N, Sonobe T. Combustion mechanism of azide polymer［J］. Propellant, Explosive and Pyrotechnical, 1988, 13:172-177.
［10］ Waesche R H W, Wenograd J. Calculation of solid-propellant burning rates from condensed-phase decomposition kinetics［J］. Combustion, Explosion and Shock Waves, 2000, 36(1): 125-134.

[1]	霍俊达, 闫振展, 鲁月文, 韩纪旻, 杨利. 多孔聚丙烯酸盐制备及对高氯酸铵热分解的催化[J]. 兵工学报, 2021, 42(6): 1215-1222.
[2]	翟禹尧，史贤俊，韩露，吕佳朋. 基于广义随机有色Petri网的测试性建模方法[J]. 兵工学报, 2021, 42(3): 655-662.
[3]	田相轩，李军旗，金丽亚，刘正仁，石志强. 基于相关性分析的指挥信息系统模拟数据集可用性评估算法[J]. 兵工学报, 2021, 42(2): 399-407.
[4]	杨梓鑫，薛源，孙畅，徐浩军，韩欣珉. 基于Elman神经网络和Copula函数的多维装备效能评估模型[J]. 兵工学报, 2020, 41(8): 1633-1645.
[5]	李宽宽，郭效德，梁力，张正金，夏亮，常志鹏. 纳米碳酸锶/高氯酸铵复合粒子的制备及其撞击感度和热分解性能研究[J]. 兵工学报, 2020, 41(7): 1317-1322.
[6]	管发扬，于兰，任慧，焦清介，刘洁. 硝化石墨烯制备及对高氯酸铵热分解的催化作用[J]. 兵工学报, 2020, 41(7): 1323-1329.
[7]	杨志远，赵建民，程中华，李俐莹，池阔. 基于退化相关性分析的竞争失效系统可靠性模型[J]. 兵工学报, 2020, 41(7): 1423-1433.
[8]	奚之飞，徐安，寇英信，李战武，杨爱武. 基于前景理论的空战目标威胁评估[J]. 兵工学报, 2020, 41(6): 1236-1248.
[9]	刘燕，安崇伟，罗进，王晶禹. 纳米六硝基六氮杂异伍兹烷与三氨基三硝基苯含能复合物的制备及性能研究[J]. 兵工学报, 2020, 41(1): 49-55.
[10]	翟禹尧，史贤俊，秦玉峰，吕佳朋. 基于层次广义随机Petri网的测试性建模新方法[J]. 兵工学报, 2020, 41(1): 161-170.
[11]	闫涛，任慧，马爱娥，焦清介，王慧心. 氟橡胶包覆层对纳米铝粉性能的影响研究[J]. 兵工学报, 2019, 40(8): 1611-1617.
[12]	张正金，郭效德，刘杰，梁力，李宽宽，夏亮，常志鹏，田淑宝，黄东彦，杨雪芹. 超细亚铁氰化铅/高氯酸铵复合粒子的制备及热分解、防团聚性能研究[J]. 兵工学报, 2019, 40(11): 2220-2228.
[13]	曹雄，张云，曹卫国，张玉龙，戴鹏，薛晨露，谭迎新. 质量效应及热历史对硝酸铵热分解特性的影响研究[J]. 兵工学报, 2018, 39(11): 2153-2158.
[14]	高飞，孙磊. 基于首达波与次达波到达时差的深海浅层移动声源定位[J]. 兵工学报, 2018, 39(11): 2243-2248.
[15]	袁俊明，张林炎，唐鑫，刘玉存，张喜亮，陈银刚，李硕. 小型传爆装置慢燃实验及数值计算[J]. 兵工学报, 2017, 38(8): 1541-1546.