三唑含能离子盐在固体推进剂中的应用研究

doi:10.3969/j.issn.1000-1093.2014.09.009

兵工学报 ›› 2014, Vol. 35 ›› Issue (9): 1388-1392.doi: 10.3969/j.issn.1000-1093.2014.09.009

三唑含能离子盐在固体推进剂中的应用研究

裴庆¹，赵凤起¹，高红旭¹，徐司雨¹，郝海霞¹，姚二岗¹，周智明²

（1.西安近代化学研究所燃烧与爆炸技术重点实验室，陕西西安 710065； 2.北京理工大学化工与环境学院，北京 100081）

收稿日期:2013-12-12 修回日期:2013-12-12 上线日期:2014-11-03
通讯作者: 裴庆 E-mail:peiqing204@sohu.com
作者简介:裴庆（1982—），男，工程师

Research on Application of Energetic Triazole Ionic Salts in Solid Propellant

PEI Qing¹， ZHAO Feng-qi¹, GAO Hong-xu¹, XU Si-yu¹， HAO Hai-xia¹, YAO Er-gang¹, ZHOU Zhi-ming²

(1.Science and Technology on Combustion and Exprosion Laboratory, Xi’an Modern Chemistry Research Institute,Xi’an 710065， Shaanxi, China；2.School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, China)

Received:2013-12-12 Revised:2013-12-12 Online:2014-11-03
Contact: PEI Qing E-mail:peiqing204@sohu.com

摘要/Abstract

摘要： 运用差示扫描量热仪（DSC）评估了4种三唑含能离子盐与固体推进剂主要组分的相容性，研究了含不同三唑含能离子盐的聚叠氮缩水甘油醚（GAP）推进剂的燃烧性能。结果表明，三唑含能离子盐与固体推进剂的主要组分GAP和硝化棉相容，而1,2,4-三唑硝酸盐（1a）、1,2,3-三唑硝酸盐（1b）、3,4,5-三氨基-1,2,4-三唑二硝酰胺盐（2b）与黑索今（RDX）及吸收药（硝化棉+硝化甘油）轻微敏感或敏感。含1,2,4-三唑硝酸盐（1a）的配方在12～16 MPa范围内具有较高的燃速，含1,2,3-三唑硝酸盐（1b）的配方在7～10 MPa范围内具有较高的燃速，3,4,5-三氨基-1,2,4-三唑硝酸盐（2a）和3,4,5-三氨基-1,2,4-三唑二硝酰胺盐（2b）可以明显地降低10～16 MPa范围内GAP推进剂的燃速压力指数。

关键词: 兵器科学与技术, 三唑含能离子盐, 相容性, 聚叠氮缩水甘油醚, 燃烧特性

Abstract: DSC thermal analysis method is employed to evaluate the compatibility of four kinds of energetic triazole ionic salts with some solid propellant main components. The effects of four energetic triazole ionic salts on the combustion properties of glycidyl azide polymer （GAP）propellant are investigated. The results indicate that four kinds of energetic triazole ionic salts have good compatibility with GAP, and nitrocellulose (NC), but they are sensitive with cyclotrimethylene trinitramine (RDX) and nitrocellulose/nitroglycerine (NC+NG) except 3,4,5-triamino-1,2,4-triazolium nitrate (2a). GAP propellant containing containing 1,2,4- triazolium nitrate (1a) has higher burining rate in the range of 12～16 MPa. GAP propellant containing 1,2,3-triazolium nitrate (1b) has higher burning rate in the range of 7～10 MPa. The burning rate pressure exponents for the propellants containing 3,4,5-triamino-1,2,4-triazolium nitrate (2a) and 3,4,5-triamino-1,2,4-triazolium dinitramide (2b) are decreased in the range of 10～16 MPa.

Key words: ordnance science and technology, energetic triazole ionic salt, compatibility, GAP, combustion characteristic

中图分类号:

TJ55

裴庆，赵凤起，高红旭，徐司雨，郝海霞，姚二岗，周智明. 三唑含能离子盐在固体推进剂中的应用研究[J]. 兵工学报, 2014, 35(9): 1388-1392.

PEI Qing， ZHAO Feng-qi, GAO Hong-xu, XU Si-yu， HAO Hai-xia, YAO Er-gang, ZHOU Zhi-ming. Research on Application of Energetic Triazole Ionic Salts in Solid Propellant[J]. Acta Armamentarii, 2014, 35(9): 1388-1392.

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三唑含能离子盐在固体推进剂中的应用研究

Research on Application of Energetic Triazole Ionic Salts in Solid Propellant

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