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Acta Armamentarii ›› 2022, Vol. 43 ›› Issue (11): 2916-2923.doi: 10.12382/bgxb.2022.0594

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Processing and Characteristics of Polytetrafluoroethylene Based Electromagnetic Shielding Composite Films

JIA Rufeng1, YIN Baolin1,2, ZHANG Gaohong3, PANG Xinchang1, LIU Minying1, YANG Guofang2, LI Hao3, L Qianli3   

  1. (1.School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450000, Henan, China; 2.Zhengzhou High-Tech Polymer Technology Co., Ltd. Zhengzhou 450000, Henan, China; 3.Henan Aerospace Hydraulic& Pneumatic Technology Co., Ltd. Zhengzhou 450000, Henan, China)
  • Online:2022-07-29

Abstract: Polytetrafluoroethylene (PTFE) based composite films with high electrical conductivity, great deformability and high electromagnetic shielding property were prepared using liquid metal (EGaIn@Ag), silver flakes and multi-wall carbon nanotubes as hybrid conductive fillers. The mechanical, electrical and electromagnetic shielding properties of the composite films were investigated comprehensively. The results showed that the composite films possess great mechanical properties with the elongation at break of more than 250% and the tensile strength of 18.1 MPa, and the square resistance of the composite film can be as low as 5.34 Ω/sq. With the addition of EGaIn@Ag, the change rate of resistance can be effectively reduced during tensile deformation. The electromagnetic shielding efficiency (EMI SE) of the PTFE based composite film can reach up to 60.5 dB. At 10% tensile strain, the EMI SE of the composite film with the same amount of Ag and EGaIn@Ag was still 41.6 dB, while the EMI SE of the composite film with only silver sheet added was 26.8 dB. These demonstrate that the composite film with EGaIn@Ag has good EMI shielding performance even at a large deformation, possessing good application prospects.

Key words: polytetrafluoroethylene, compositefilms, liquidmetal, mechanicalproperty, electromagneticshielding

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