基于近红外技术的火药安定期评价新方法

doi:10.3969/j.issn.1000-1093.2018.03.007

摘要/Abstract

摘要： 为解决现存火药安定性评价方法安全性差、操作繁琐、耗时等问题，提出一种火药安定期评价新方法。采用热加速老化方法获取不同安定剂含量的实验试样，开展火药老化的动力学方程研究。借助近红外技术与化学计量学方法建立了安定剂含量的近红外定量模型，经过对模型的分析和优化得到安定剂含量的最佳定量模型。实例应用结果表明:该模型的决定系数R²为0.999 6，预测最大误差低于0.04%，证明了该模型具有高度可行性，可实现火药安定期的无损、快速、实时评估。

关键词: 火药, 安定期, 安定剂, 近红外技术, 评价

Abstract: A new approach to evaluate the stability period of propellant is presented to solve the problems of poor safety, fussy operation and time-consuming of the existing methods for evaluating the stability of propellants. The propellant samples with different stabilizer contents were prepared by thermal accelerated aging test, and the kinetic equation of propellant aging was studied. A quantitative model for the determination of stabilizer content in propellant is established using near-infrared spectroscopy and chemometrics algorithm. The best quantitative model is obtained by analyzing and optimizing the proposed model. Applied results show that the determination coefficient (R²) of the model is 0.999 6, and the maximum predicted error is no larger than 0.04%. It proves that the proposed model can be used for the nondestructive, rapid and real-time evaluation of the stability period of propellant. Key

Key words: propellant, stabilityperiod, stabilizer, near-infraredspectroscopytechnique, evaluation

中图分类号:

周静，丁黎，张俊林，安静，祝艳龙，梁忆. 基于近红外技术的火药安定期评价新方法[J]. 兵工学报, 2018, 39(3): 463-467.

ZHOU Jing, DING Li, ZHANG Jun-lin, AN Jing, ZHU Yan-long, LIANG Yi. New Approach for Evaluating the Stability Period of Propellant Based on Near-infrared Spectroscopy[J]. Acta Armamentarii, 2018, 39(3): 463-467.

参考文献

［1］张力, 杜仕国, 许路铁,等. 甲基紫试验在长贮火药安定性检测中的应用[J]. 火炸药学报, 2006, 29(6):74-76.
ZHANG Li, DU Shi-guo, XU Lu-tie, et al. Application of methyl- violet test in storage stability of propellants[J]. Chinese Journal of Explosives & Propellants, 2006, 29(6):74-76.（in Chinese）
[2］ Mahmed B. Chemical compatibility study of gap based propellant by the DVST[J]. Journal of Energetic Materials, 1993, 11(2):119-134.
[3］ Ganev R, Glavchev I. Investigation of the stability of a mixture of single-based propellants and resins or polymers[J]. Journal of Hazardous Materials, 2002, 90(1):19-24.
[4］ Klerk W P C D, Boers M N. Sample geometry as critical factor for stability research[J]. Thermochimica Acta, 2003, 401(1):43-52.

[5］ Whipple R. Field analysis of propellant stabilizers and their daughter products in any propellant formulation by thin-layer chromatography year end report 2003, UCRL-TR-201359[R]. Livermore, CA, US: Lawrence Livermore National Laboratory, 2003.
[6］ Davies A M C. William Herschel and the discovery of near infrared[J]. Journal of Near Infrared Spectroscopy, 2000, 11(1):3-5.
[7］ Brackett F S.Characteristic differentiation in the spectra of saturated hydrocarbons[J].Proceedings of the National Academy of Sciences of the United States of America,1928, 14(11):857-864.
[8］齐晓, 韩建国, 李曼莉. 近红外光谱分析仪器的发展概况[J]. 光谱学与光谱分析, 2007, 27(10):2022-2026.
QI Xiao, HAN Jian-guo,LI Man-li. Survey of the development of near-infrared spectroscopy instruments[J]. Spectroscopy & Spectral Analysis, 2007, 27(10):2022-2026. （in Chinese）
[9］王多加, 周向阳, 金同铭,等. 近红外光谱检测技术在农业和食品分析上的应用[J]. 光谱学与光谱分析, 2004, 24(4):447-450.
WANG Duo-jia, ZHOU Xiang-yang, JIN Tong-ming, et al. Application of near-infrared spectroscopy to agriculture and food analysis[J]. Spectroscopy & Spectral Analysis, 2004, 24(4):447-450.（in Chinese）

[10］ Wang D J, Zhou X Y, Jin T M, et al. Application of near-infrared spectroscopy to agriculture and food analysis[J]. Spectroscopy & Spectral Analysis, 2004, 24(4):447-450.
[11］ Bohacs G, Ovadi Z, Salgó A. Prediction of gasoline properties with near infrared spectroscopy[J]. Near Infrared Spectroscopy, 1998, 6(1): 341-348.
[12］ Choquette S J, Travis J C, O'Neal L E, et al. A rare-earth-oxide glass for the wavelength calibration of near-infrared dispersive and Fourier-transform spectrometers[J].Spectroscopy, 2001, 16(4): 14-19.
[13］邢志娜, 王菊香, 申刚,等. 改进偏最小二乘法在航空煤油的近红外光谱分析中的应用[J]. 兵工学报, 2010, 31(8):1106-1109.
XING Zhi-na, WANG Ju-xiang, SHEN Gang, et al. Application of improved partial least squares method in near-infrared spectrum analysis for aviation kerosene [J]. Acta Armamentarii, 2010, 31(8): 1106-1109.(in Chinese)
[14］ Lysaght M J, Kelly J J, Callis J B. Rapid spectroscopic determination of per cent aromatics, per cent saturates and freezing point of JP-4 aviation fuel[J]. Fuel, 1993, 72(5): 623-631.
[15］ Tujjar O, Gaudio A R D, Tofani L, et al. Effects of prolonged ischemia on human skeletal muscle microcirculation as assessed by near-infrared spectroscopy[J]. Journal of Clinical Monitoring & Computing, 2017, 31(3):581-588.
[16］ Hirasawa A, Kaneko T, Tanaka N, et al. Near-infrared spectroscopy determined cerebral oxygenation with eliminated skin blood flow in young males.[J]. Journal of Clinical Monitoring & Computing, 2016, 30(2):1-8.
[17］ Singh B R. Basic aspects of the technique and applications of infrared spectroscopy of peptides and proteins[J]. ACS Symposium Series, 1999, 750(4):2-37.
[18］邹权, 邓国栋, 郭效德, 等. 近红外在线监测改性双基吸收药混合均匀度研究[J]. 兵工学报, 2014, 35(7):977-981.
ZOU Quan, DENG Guo-dong, GUO Xiao-de, et al. Research on near-infrared online monitoring for blend uniformity of modified double-base absorbent powders[J].Acta Armamentarii, 2014, 35(7):977-981.（in Chinese）

第39卷
第3期2018 年3月兵工学报ACTA
ARMAMENTARIIVol.39No.3Mar.2018

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