Cr12MoV冷作模具钢渗硼层表面与界面分析

doi:10.3969/j.issn.1000-1093.2015.03.028

兵工学报 ›› 2015, Vol. 36 ›› Issue (3): 571-576.doi: 10.3969/j.issn.1000-1093.2015.03.028

• 研究简报 • 上一篇

Cr12MoV冷作模具钢渗硼层表面与界面分析

孔德军^1,2，谢春洋¹

(1.常州大学机械工程学院江苏常州 213164; 2.常州大学江苏省材料表面科学与技术重点实验室江苏常州 213164)

收稿日期:2014-05-28 修回日期:2014-05-28 上线日期:2015-05-01
通讯作者: 孔德军 E-mail:kongdejun@163.com
作者简介:孔德军(1966—)男副教授硕士生导师博士
基金资助:
江苏省科技支撑计划(工业)项目(BE2014818)；中国学位与研究生教育学会研究课题(C1-2013Y07-051)

Analysis of Surface-interface of Boronized Layer on Cr12MoV Cold-worked Die Steel

KONG De-jun^1,2, XIE Chun-yang¹

(1.College of Mechanical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China;2.Jiangsu Key Laboratory of Materials Surface Science and Technology,Changzhou University, Changzhou 213164, Jiangsu, China)

Received:2014-05-28 Revised:2014-05-28 Online:2015-05-01
Contact: KONG De-jun E-mail:kongdejun@163.com

摘要/Abstract

摘要： 采用热浸渗法对Cr12MoV冷作模具钢进行渗硼处理，通过扫描电镜、能量色谱和X射线衍射分析渗硼层表面-界面形貌、化学元素分布和物相组成，对结合界面进行线扫描和面扫描分析，讨论了热浸法渗硼机理，并对残余应力和残余奥氏体进行测试。测试结果表明：渗硼层表面存在着细小气孔，与不溶于硼化物的原子扩散相关；渗硼层表面形成的高硬FeB按照(002)方向择优生长；渗硼层结合界面化学元素发生相互扩散，元素分布均匀；渗硼处理后表面残余应力由拉应力变为压应力，同时残余奥氏体转变为马氏体，改善了冷作模具的摩擦与磨损性能。

关键词: 材料表面与界面, Cr12MoV钢, 渗硼处理, 表〖JP9〗面-〖JP〗界面, 残余应力, 残余奥氏体

Abstract: The surface of Cr12MoV cold-worked die steel is boronized by the method of hot-dipping, and the surface and interface morphologies and the chemical and phase compositions are analyzed by SEM, EDS and XRD, respectively. The residual stress and retained austenite on the surface are analyzed, and the hot-dipped boronizing mechanism is discussed. The results show that the tiny pores exist on the surface of boronized layer, and are related to the elements which are not solubled in boride. FeB is formed in the diffusion layer that has a preferred orientation in crystal plane (002), and the chemical reactions and mutual diffusion of elements occur in the layer. The surface residual stress is changed from tensile stress to compressive stress, and the retained austenite is transformed into martensite after boronizing, which improves the friction and wear properties of cold-worked die steel.

Key words: surface and interface of material, Cr12MoV, boronizing treatment, surface-interface, residual stress, retained austenite

中图分类号:

孔德军，谢春洋. Cr12MoV冷作模具钢渗硼层表面与界面分析[J]. 兵工学报, 2015, 36(3): 571-576.

KONG De-jun, XIE Chun-yang. Analysis of Surface-interface of Boronized Layer on Cr12MoV Cold-worked Die Steel[J]. Acta Armamentarii, 2015, 36(3): 571-576.

参考文献

［1］赵彦辉, 巴宏波, 郎文昌, 等. 电弧等离子体辅助渗氮处理Cr12MoV钢的组织结构及硬度[J]. 材料热处理学报, 2012, 33(10):151-154.
ZHAO Yan-hui, BA Hong-bo, LANG Wen-chang, et al. Microstructure and hardness of Cr12MoV steel treated by arc plasma assisted nitriding process[J]. Transactions of Materials and Heat Treatment, 2012, 33(10):151-154.（in Chinese)
[2] Li S H, Xie Y Z, Wu X C. Hardness and toughness investigations of deep cryogenic treated cold work die steel[J]. Cryogenics, 2010, 2(2):89-92.
[3] Uslu I, Comert H, Ipek M, et al. A comparison of borides formed on AISI 1040 and AISI P20 steels[J]. Materialsand Amp, 2007, 28(6):1819-1826.
[4] 苏振国, 安健, 田旭, 等. 稀土粉末渗硼45钢的磨损与腐蚀性能[J]. 材料热处理学报, 2009, 30(12):183-190.
SU Zhen-guo, AN Jian, TIAN Xu, et al.Wear and corrosion properties of 45 steel boronized using Nd₂O₃ as activator[J]. Transactions of Materials and Heat Treatment, 2009, 30(12): 183-190.（in Chinese)
[5] 孔德军, 周朝政. Cr12MoV冷作模具钢TD处理后VC涂层的组织和性能[J]. 中国矿业大学学报, 2011, 40(1):162-166.
KONG De-jun, ZHOU Chao-zheng.Structures and properties of VC coating on Cr12MoV cold working die steel by TD process[J]. Journal of China University of Mining & Technology, 2011, 40(1): 162-166.（in Chinese）
[6] 姜训勇, 刘智勇, 朱穗东. 渗硼对45钢耐液态金属腐蚀性能影响的研究[J]. 材料热处理学报, 2005, 26(2): 99-102.
JIANG Xun-yong, LIU Zhi-yong, ZHU Hui-dong. Research of influence of borinizing treatment on corrosion resistance of 45 steel in molten metal[J]. Transactions of Materials and Heat Treatment, 2005, 26(2):99-102.（in Chinese)
[7] 周升, 伍婵娟, 姜佩璐, 等. 渗硼层对SUS304不锈钢耦合变形的摩擦行为的影响[J]. 材料热处理学报, 2010, 31(6): 122-127.
ZHOU Sheng, WU Chan-juan, JIANG Pei-lu, et al.Friction behavior of SUS304 stainless steel against boride layer under condition of coupling friction with deformation[J]. Transactions of Materials and Heat Treatment, 2010, 31(6):122-127.（in Chinese)
[8] 詹斌, 刘宁, 李彬彬, 等. 渗硼对Ti (C, N)基金属陶瓷组织和性能的影响[J]. 材料热处理学报, 2012, 33(8): 134-139.
ZHAN Bin, LIU Ning, LI Bin-bin, et al.Effect of boronizing on microstructure and properties of Ti(C, N)-based cermet[J]. Transactions of Materials and Heat Treatment, 2012, 33(8):134-139. （in Chinese)
[9] 王禹, 陈旻, 郜嘉平, 等. Ti-Cr-Si硅化物涂层结构及裂纹扩展[J]. 稀有金属材料与工程, 2000, 29(5): 315-320.
WANG Yu, CHEN Min, GAO Jia-ping, et al. Microstructure and crack propagation of Ti-Cr-Si silicide coatings on the niobium alloy C-103[J]. Rare Metal Materials and Engineering, 2000, 29(5):315-320.（in Chinese)
[10] 殷磊, 易丹青, 肖来荣, 等. 铌表面MoSi₂高温涂层的形貌和结构研究[J]. 稀有金属材料与工程, 2005, 34(1): 91-94.
YIN Lei, YI Dan-qing, XIAO Lai-rong, et al.The morphology and structure of MoSi₂ high temperature coating on niobium[J]. Rare Metal Materials and Engineering, 2005, 34(1):91-94.（in Chinese)
[11] 衣晓红, 樊占国, 张景垒, 等. Ti-6A1-4V钛合金固体渗硼法表面改性[J]. 材料热处理学报, 2010, 31(9): 119-123.
YI Xiao-hong, FAN Zhan-guo, ZHANG Jing-lei, et al.Surface modification of Ti-6Al-4V alloy by pack boronizing[J]. Transactions of Materials and Heat Treatment, 2010, 31(9):119-123.（in Chinese)
[12] 王宏宇, 赵玉凤, 徐晓静, 等. 热处理对65Mn钢表面渗硼层组织和性能的影响[J]. 材料热处理学报, 2012, 33(12): 142-146
WANG Hong-yu, ZHAO Yu-feng, XU Xiao-jing, et al. Effects of heat treatment on microstructure and properties of boriding layer on 65Mn steel[J]. Transactions of Materials and Heat Treatment, 2012, 33(12):142-146.（in Chinese)
[13] 雷明凯, 罗鹏, 高峰, 等. 钢渗硼表面残余应力的数值分析[J]. 金属学报, 2002, 38(1): 47-52.
LEI Ming-kai, LUO Peng, GAO Feng, et al. Numerical analysis of residual stress for borided surface on steel[J]. Acta Metallurgica Sinica, 2002, 38(1):47-52.（in Chinese)
[14] 赵琳, 张旭东, 陈武柱. 800 MPa级低合金钢焊接热影响区韧性的研究[J]. 金属学报, 2005, 41(4): 392-396.
ZHAO Lin, ZHANG Xu-dong, CHEN Wu-zhu.Toughness of heat-affected zone of 800 MPa grade low alloy steel[J]. Acta Metallurgica Sinica, 2005, 41(4):392-396.( in Chinese)

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Cr12MoV冷作模具钢渗硼层表面与界面分析

Analysis of Surface-interface of Boronized Layer on Cr12MoV Cold-worked Die Steel

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