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TiH2粉末/环氧丙烷/空气混合物三相爆燃特性实验研究

刘蓉1,汪旭光1,2,蒋八运2,汪泉1,2,程扬帆1,2*   

  1. 1. 安徽理工大学 土木建筑学院, 安徽 淮南232001; 2. 安徽理工大学 化工与爆破学院, 安徽 淮南232001
  • 收稿日期:2024-12-13 修回日期:2025-03-19
  • 基金资助:
    安徽省高校杰出青年科研项目(2023AH020026);国家自然科学基金面上项目(12272001)

Experimental Study on Solid-liquid-gas Three-phase Deflagration Characteristics of TiH2 Powders/epoxypropane/air Mixture

LIU Rong1, WANG Xuguang1,2, JIANG Bayun2, WANG Quan1,2, CHENG Yangfan1,2*   

  1. 1. School of Civil Engineering and Architecture, Anhui University of Science and Technology, Huainan 232001, Anhui, China; 2. School of Chemical Engineering and Blasting, Anhui University of Science and Technology, Huainan 232001, Anhui, China
  • Received:2024-12-13 Revised:2025-03-19

摘要: 为研究储氢材料TiH2的特征参数对环氧丙烷(PO)云雾爆轰性能的影响,制备了添加不同粒径(5.40 μm、20.72 μm、38.88 μm和60.51 μm)和不同含量(0、15%、30%、45%和60%)TiH2粉末的PO基混合燃料样品。利用20 L球形液体燃料爆炸测试系统和比色测温技术,研究TiH2粉末/PO/空气混合燃料固-液-气三相爆燃特性,并与Ti粉末/PO/空气混合燃料进行比较。实验结果表明:相较于Ti粉末/PO/空气混合燃料,TiH2粉末/PO/空气混合燃料的火焰传播速度、冲击波峰值压力以及火焰平均温度增加;随着TiH2粉末粒径的增加,TiH2粉末/PO/空气混合燃料的冲击波峰值压力、最大压力上升速率和火焰传播速度总体上均呈现持续下降的趋势,而燃烧持续时间的则持续上升;随着TiH2粉末含量的增加,TiH2粉末/PO/空气混合燃料的冲击波峰值压力、最大压力上升速率和火焰传播速度总体上均先上升后下降,而燃烧持续时间的变化趋势则与之相反。储氢材料TiH2能够显著改善PO的毁伤性能,但其特征参数对于爆轰参数和燃烧持续时间两者的影响呈相反的变化趋势,在云爆武器配方设计中需要统筹兼顾。

关键词: 云爆弹, 环氧丙烷, 储氢材料, 火焰速度, 云雾爆轰

Abstract: To study the effects of characteristic parameters of hydrogen storage material TiH2 on the detonation performance of epoxypropane (PO) cloud, PO-based mixed fuel samples with different particle sizes (5.40, 20.72, 38.88 and 60.51 μm) and different contents (0, 15 mass%, 30 mass%, 45 mass% and 60 mass%) of TiH2 powders were prepared. Using a 20 L spherical liquid fuel explosion test system and the colorimetric temperature measurement technology, the solid-liquid-gas three-phase deflagration characteristics of TiH2 powders/PO/air mixture were studied and compared with Ti powders/PO/air mixture. The experimental results showed that the flame propagation velocity, shock wave peak pressure and average flame temperature of TiH2 powders/PO/air mixture all increased when compared with Ti powders/PO/air mixture. With the increasing particle size of TiH2 powders, the shock wave peak pressure, maximum pressure rise rate and flame propagation velocity of TiH2 powders/PO/air mixture showed a trend of continuous decline, while the combustion duration continued to increase. With the increase of TiH2 powders content, the shock wave peak pressure, the maximum pressure rise rate and the flame propagation velocity of the TiH2 powders/PO/air mixture increased at first and then decreased, while the combustion duration showed an opposite trend. Hydrogen storage material TiH2 could significantly improve the damage performance of PO. However, the influence of its characteristic parameters on detonation parameters and combustion duration is opposite, so it is necessary to take overall consideration in the formulation design of cloud explosive weapons.

Key words: fuel air explosive, epoxypropane, hydrogen storage material, flame speed, cloud detonation

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