温敏光子晶体结构色调控

doi:10.3969/j.issn.1000-1093.2020.08.012

兵工学报 ›› 2020, Vol. 41 ›› Issue (8): 1573-1580.doi: 10.3969/j.issn.1000-1093.2020.08.012

温敏光子晶体结构色调控

乔宇¹，张峰²，孟子晖²，王飘飘²，邱丽莉²

（1.北方工业大学机械与材料工程学院, 北京 100144; 2. 北京理工大学化学与化工学院, 北京 100081)

收稿日期:2020-04-17 修回日期:2020-04-17 上线日期:2020-09-23
作者简介:乔宇(1987—), 男, 副教授，硕士生导师。 E-mail: 499904295@qq.com
基金资助:
北京市社会科学基金项目（18YTC025）；北方工业大学青年毓优人才培养计划项目（2018年）

Adjusment and Control of Structural Color of Thermochromic Photonic Crystal Material

QIAO Yu¹, ZHANG Feng², MENG Zihui², WANG Piaopiao², QIU Lili²

(1.School of Mechanical and Materials Engineering, North China University of Technology, Beijing 100144, China; 2.School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China)

Received:2020-04-17 Revised:2020-04-17 Online:2020-09-23

摘要/Abstract

摘要： 为满足现代战争对军用设备视觉隐身的需求，设计了一种具有环境自适应性,制备涂装简单,制作过程绿色环保的光子晶体温敏变色材料。采用乳液聚合法制备粒径分别为132 nm、205 nm、 275 nm、 300 nm的聚苯乙烯微球，并将其垂直沉降自组装形成结构高度有序、结构色明显的三维聚合物光子晶体。对温度敏感的聚N-异丙基丙烯酰胺/丙烯酰胺水凝胶与聚苯乙烯三维光子晶体相结合，制备出结构色随环境温度发生改变的光子晶体凝胶膜。基于色度、饱和度、亮度色彩模式，通过实验分析验证了该材料颜色可随环境温度变化做出响应。结果表明，光子晶体温敏变色材料可以实现环境温度自适应响应，在视觉伪装方面具有一定的应用前景。

关键词: 光子晶体, 温度响应, 视觉隐身, 结构色

Abstract: A camouflage material with environmental adaptability, simple preparation and painting, and green production process was designed to meet the visual stealth requirements of military equipment. The polystyrene microspheres with diameters of 132 nm, 205 nm, 275 nm and 300 nm were prepared by using emulsion polymerization. Three-dimensional photonic crystals with highly ordered structure and obvious structural color were prepared by using vertical sedimentation self-assembly method. The temperature-sensitive PNIPAM/AM hydrogel and polystyrene three-dimensional photonic crystal were used to prepare a photonic crystal gel film with structural color changing with ambient temperature. Based on the analysis of HSB (hues, saturation, brightness) color model, it is verified that the color of the material can respond with the change of environment temperature. The results show that the thermochromic photonic crystal material can achieve adaptive response to ambient temperature and has certain application prospects in visual stealth.

Key words: photoniccrystal, temperatureresponse, visualstealth, structuralcolor

中图分类号:

TB339

乔宇，张峰，孟子晖，王飘飘，邱丽莉. 温敏光子晶体结构色调控[J]. 兵工学报, 2020, 41(8): 1573-1580.

QIAO Yu, ZHANG Feng, MENG Zihui, WANG Piaopiao, QIU Lili. Adjusment and Control of Structural Color of Thermochromic Photonic Crystal Material[J]. Acta Armamentarii, 2020, 41(8): 1573-1580.

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温敏光子晶体结构色调控

Adjusment and Control of Structural Color of Thermochromic Photonic Crystal Material

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