欢迎访问《兵工学报》官方网站,今天是 分享到:

兵工学报 ›› 2013, Vol. 34 ›› Issue (11): 1448-1453.doi: 10.3969/j.issn.1000-1093.2013.11.017

• 论文 • 上一篇    下一篇

钛基金属氧化物涂层电极的制备及表征

张丽, 关江勇, 韩卫清, 王连军   

  1. (南京理工大学 环境与生物工程学院, 江苏 南京 210094)
  • 收稿日期:2012-12-28 修回日期:2012-12-28 上线日期:2014-01-22
  • 作者简介:张丽(1962—),女,副教授。
  • 基金资助:
    兵器预先研究项目(2012)

Preparation and Characterization of Titaniumbased Metal Oxide Coated Electrodes

ZHANG Li, GUAN Jiang-yong, HAN Wei-qing, WANG Lian-jun   

  1. (School of Environmental and Biological Engineering, Nanjing University of Science and Technology,Nanjing 210094, Jiangsu, China)
  • Received:2012-12-28 Revised:2012-12-28 Online:2014-01-22

摘要: 为了对化工废水进行处理,以Ti/SnSb电极为基础,采用刷涂热解法制备出掺杂Fe、Mn、Ni、Ru和Co等元素的钛基涂层电极。Sn、Sb和X(X代表掺杂元素)按照原子质量比为100∶10∶5的比例配制涂液,在475℃高温下煅烧。用SEM、XRD和电化学工作站等分析方法分析了改性电极的表面形貌、析氧电位值和使用寿命等因素。分析结果表明:阳极表面活性涂层易产生“龟裂”现象,影响电极的催化活性和使用寿命。与掺杂其他元素的改性电极相比,Ti/SnSbMn电极的使用寿命最长,更难析出氧气,污染物更容易被氧化降解。

关键词: 电化学工程, 掺杂改性, 钛基体, 电催化活性, 废水处理

Abstract: On basis of Ti/SnSb doped electrodes, the doping elements, including Fe, Mn, Ni, Ru and Co,are used to prepare the Tibased electrodes by thermal brushing decomposition. The coating solution is prepared according to the atomic mass ratio of Sn, Sb and X(X representing a doping element) of 100∶10∶5. Then the electrodes are calcined at 475℃. The electrocatalytic performance of doped electrodes is studied. The results show that the thermal brushing decomposition could easily lead to a “cracking” phenomenon on the surface of the active coating, affecting the catalytic activity and lifetime of electrode. Compared with other doped electrodes, Ti/SnSbMn doped electrode has the longest lifetime.

Key words: electrochemistry engineering, doping, titanium matrix, electrocatalytic activity, wastewater treatment

中图分类号: