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基于MXene的复合织物多功能设计与实验表征

陈婧1,于馨茗2,刘宇航1,周宏元3,黄广炎1,4,张宏1,4*   

  1. 1.北京理工大学 爆炸科学与安全防护全国重点实验室,北京 100081; 2.伦敦大学学院 数学与物理科学学院,伦敦 WCE1 6BT; 3. 北京工业大学 城市建设学部, 北京 100124; 4. 北京理工大学重庆创新中心 现代兵器技术实验室,重庆 401120
  • 收稿日期:2024-09-18 修回日期:2025-01-18
  • 基金资助:
    面上基金项目(12372354);自然基金委创新群体项目(12221002)

Multifunctional Design and Experimental Characterization of MXene-Decorated Composite Fabrics

CHEN Jing1, YU Xinming2, LIU Yuhang1, ZHOU Hongyuan3, HUANG Guangyan1,4, ZHANG Hong1,4 *   

  1. 1. State Key Laboratory of Explosion Science and Safety Protection, Beijing Institute of Technology, Beijing 100081, China; 2. Faculty of Mathematical and Physical Sciences, University College London, London WCE1 6BT, England; 3.Faculty of Architecture, Civil and Transportation Engineering, Beijing University of Technology, Beijing 100124, China; 4. Modern Weapon Technology Laboratory Beijing Institute of Technology Chongqing Innovation Center, Chongqing 401120, China
  • Received:2024-09-18 Revised:2025-01-18

摘要: 现代战场环境具有复杂性和多变性,人员和装备面临高寒、电磁辐射和子弹冲击等多样化威胁,因此有必要研发轻质便携的多功能防护材料,进一步保障作战人员和武器装备的安全。物理叠加单一功能织物实现多功能集合会造成材料成本和质量的严重增加,目前已有对织物的多功能开发和研究,但还未有多功能织物将防水、电磁屏蔽、阻燃、光发热、钝伤防护五种战场所需功能集合于一体。采用MXene材料作为功能层,芳纶织物(Twaron)作为基础材料,有机硅胶作为表面防水层,制作多功能一体化材料MS-Twaron。接触角测试、电磁屏蔽测试、阻燃测试、弹道实验和光热实验的实验结果表明:1)相比于亲水材料Twaron(接触角为29.7°),MS-Twaron具有良好的疏水性能(接触角为112.3°);2)相比于完全不具有电磁屏蔽性能的Twaron,MXene质量分数为8.61%的MS-Twaron在X波段总电磁屏蔽效能提升至13.490 ~14.969 dB;3)对比Twaron,MS-Twaron的余焰时间增加5.0 s,但阴燃时间缩短3.5 s,平均损坏长度减小5.3 mm;4)MS-Twaron具有抗钝伤的性能(弹道冲击的凹陷深度比Twaron小6.12 mm);5)对比没有光热性能的Twaron,自然光(光强100.3×103 LUX)照射后,MS-Twaron表面温度高达50.22 ℃;白炽灯(100 w,30 cm)照射后,MS-Twaron温度上升至39.58 ℃;红外灯(375 w,40 cm)照射后,MS-Twaron能达到97.18 ℃的高温。MS-Twaron凭借轻质、光发热、电磁屏蔽等多功能一体化,可为新一代多功能防护装备的发展提供设计思路。

关键词: MXene, 光发热, 钝伤效应, 电磁屏蔽

Abstract: The modern warfare environment is complex and variable, with personnel and equipment facing diverse threats such as extreme cold, electromagnetic radiation, and ballistic impacts. Therefore, it is essential to develop lightweight and portable multifunctional protective materials to further safeguard the safety of combatants and weaponry. The physical superposition of single-function fabrics to achieve a multifunctional composite can lead to a significant increase in material costs and quality. While there has been research and development on multifunctional fabrics, there has yet to be a multifunctional fabric that integrates five battlefield-required functionalities: waterproofing, electromagnetic shielding, flame resistance, photothermal effects, and blunt force protection. MS-Twaron uses MXene materials as the functional layer and employs aramid fibers(Twaron) as the base material with silicone gel as the surface waterproof layer. The results of the contact angle test, electromagnetic interference(EMI) shielding test, flame retardancy test, ballistic test, and photothermal experiment indicate that: 1)Compared to the hydrophilic material Twaron (water contact angle of 29.7°), MS-Twaron exhibits excellent hydrophobic properties (water contact angle of 112.3°). 2)Compared to Twaron, which exhibits no EMI properties, the MS-Twaron material with an MXene mass fraction of 8.61% shows an improved EMI properties in the X-band, ranging from 13.490 dB to 14.969 dB. 3)Compared to Twaron, MS-Twaron exhibits an increase in afterglow time by 5.0 s, a reduction in glowing time by 3.5 s, and a decrease in average char length by 5.3 mm. 4)MS-Twaron has impact resistance properties. (The ballistic indentation depth of MS-Twaron is 6.12 mm smaller than that of Twaron.) 5)Compared to Twaron, MS-Twaron can achieve a surface temperature of up to 50.22 °C under natural light (intensity 100.3 × 103 LUX), 39.58 °C under incandescent light (100 W, 30 cm), and 97.18 °C under infrared light (375 W, 40 cm). With its integration of lightweight, photothermal, and EMI properties, MS-Twaron offers design insights for the next-generation multifunctional protective equipment.

Key words: MXene, photothermal property, behind armor blunt trauma, electromagnetic shielding

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