Preparation and Performances of Nano-micron Flaky Energetic Material for Integrated Device

doi:10.3969/j.issn.1000-1093.2013.08.005

Abstract

Abstract:

Flaky RDX and HMX are prepared by using solvent/ non-solvent recrystallization and soft template method in order to meet the integration requirements of energetic material in miniature explosive element. Its surface appearance is investigated by SEM. The result shows that the thickness and length of hexagonal flaky RDX crystal are about 3 μm and 20 -50 μm, respectively; the thickness and length of quadrilateral RDX flaky crystal are approximately 1 μm and 10 -50 μm, respectively; the thickness and length of rectangle HMX flaky crystal are less than 1 μm and 3 -10 μm, respectively. The impact sensi- tivity and thermal decomposition of flaky energetic material crystal are tested. The test results show that the impact sensitivity of flaky energetic material crystal is increased, but its exothermal peak value is not changed compared with near-spherical crystal.

Key words: ordnance science and technology, nano-micro structure, soft template, energetic material plate

CLC Number:

TJ55

WANG Jian-hua, LIU Yao, YAN Li-wei, LIU Yu-cun, CHANG Shuang-jun, YU Yan-wu. Preparation and Performances of Nano-micron Flaky Energetic Material for Integrated Device[J]. Acta Armamentarii, 2013, 34(8): 953-957.

References

[1] 聂福德, 杨光成, 黄辉. 含能材料的微纳米化与器件集成化[C]//含能材料与钝感弹药技术学术研讨会论文集. 成都:中国工程物理研究院化工材料研究所, 2010: 39 -40. NIE Fu-de, YANG Guang-cheng, Huang Hui. Microstructure energetic materials and technology of integration devices[C]//Energetic Materials and Insensitive munitions Technical Symposium.Chengdu:Institute of Chemical Materials, China Academy of Engineering Physics, 2010: 39 -40. (in Chinese) [2] Rossi C, Zhang K, Esteve D, et al. Nanoenergetic materials for MEMS: a review[J]. Journal of Microelectromechanical Systems,2007, 16(4): 919 -931. [3] 王晓丽, 焦清介, 李国新. 蒸镀太安薄膜的机理研究[J]. 北京理工大学学报, 2004, 24(3): 276 -279. WANG Xiao-li, JIAO Qing-jie, LI Guo-xin. Mechanism of evaporating PETN explosive film[J]. ransactions of Beijing Institute of Technology, 2004, 24(3): 276 -279. (in Chinese) [4] Chen J, Qiao Z, Wang L, et al. Fabrication of rectangular 2, 6- diamino-3, 5-dinitropyrazine-1-oxide Microtubes [ J]. Materials Letters, 2011, 65(6): 1018 -1021. [5] 张敏, 岳璞, 李剑利, 等. β-环糊精与NTO 钡盐复合物纳米线的制备与表征[J]. 含能材料, 2007,15(1):67 -69. ZHANG Min, YUE Pu, LI Jlan-li, et al. Preparation and characterization of a novel nanotube of β-CD with (NTO)2 Ba[J]. Chinese Journal of Energetic Materials, 2007, 15(1): 67 - 69. (in Chinese) [6] 陶新永, 张孝彬, 孔凡志, 等. PEG 辅助氧化锌纳米棒的水热法制备[J]. 化学学报, 2004,62(17):1658 -1662. TAO Xin-yong, ZHANG Xiao-bin, KONG Fan-zhi, et al. PEG assisted hydrothermal synthesis of ZnO nanorods[J]. Acta Chimica Sinica, 2004, 62(17): 1658 - 1662. (in Chinese) [7] 田德余,赵风起,刘剑洪. 含能材料及相关物手册[M]. 北京:国防工业出版社,2011:168 -169. TIAN De-yu, ZHAO Feng-qi, LIU Hong-jian. Handbook of energetic materials and the related compounds, Beijing: National Defence Industry Press, 2011:168 -169. (in Chinese) [8] 候聪花, 王晶禹, 张景林. 炸药内相容性测试方法的研究[J]火工品. 2010, (3):51 -53. HOU Cong-hua, WANG Jing-yu, ZHANG Jing-lin. Study on testing method of explosive's internal compatibility[J]. Initiators & Pyrotechnics, 2010, (3):51 -53. (in Chinese) [9] 储绍华. 醋酐法制备奥托金/ 黑索金研究(分离部分)[J]. 火炸药, 1979, (2): 25 -38. CHU Shao-hua. Preparation of HMX/ RDX by Acetic anhydride (separation part) [J]. Chinese Journal of Explosives & Propellants, 1979, (2): 25 -38. (in Chinese)

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