欢迎访问《兵工学报》官方网站,今天是

兵工学报 ›› 2009, Vol. 30 ›› Issue (9): 1198-1201.

• 论文 • 上一篇    下一篇

氟化物对Mg/NaN03富燃料推进剂燃烧性能的影响

邹美帅1,郭晓燕1,朱立勋2,杨荣杰1   

  1. 1.北京理工大学材料学院,北京100081;2.惠安化学工业公司,陕西西安710302
  • 收稿日期:2008-05-26 上线日期:2014-12-25
  • 通讯作者: 邹美帅 E-mail:zouzou1211@,bit.edu.cn
  • 作者简介:邹美帅(1982-),男,博士研究生。

Influence of Fluorides on Combustion Characteristics of Mg/NaNO3 Fuel-rich Propellants

ZOU Mei-shuai1, GUO Xiao-yan1, ZHU Li-xun2,YANG Rong-jie1   

  1. 1. School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China; 2. Huian Chemical Industry Company, Xi’an 710302, Shaanxi, China
  • Received:2008-05-26 Online:2014-12-25
  • Contact: ZOU Mei-shuai E-mail:zouzou1211@,bit.edu.cn

摘要: 为改善推进剂的燃烧、点火性能,降低燃烧过程中的团聚,应用不同的实验处理方法将不同的氟化物添加入Mg/NaN03富燃料推进剂体系中,在燃烧室内氮气加压下点燃推进剂,收集固体燃烧产物,研究了氟化物对于体系燃烧特性的影响;SEM电镜分析了MglNaN03体系燃烧产物团聚的情况;对比了添加氟化物后体系燃烧产物的颗粒度;分析了不同氟化物的不同影响机理。结果表明,体系外加5%氟化物后,不同程度地降低了体系的燃速,改变了燃烧产物颗粒度分布,氟化镁的生成有利于降低产物的团聚程度。

关键词: 应用化学 , 团聚 , 氟化物 , 燃烧速率

Abstract: Several kinds of fluorides were mixed into Mg/NaNO3 fuel-rich propellants by the different experimental methods for improving combustion and ignition performances, decreasing agglomeration of the metal. Burning rates of the propellants were measured. Solid combustion products of tne Mg/ NaNO3 composites mixed by fluorides were collected and analyzed by SEM and XPS. And the particle size distributions of solid combustion products were compared among the different formulations; and the effect action mechanisms of the different fluorides were analyzed. The experimented results show that burning rate of the propellants were decreased, the particle size of solid combustion products were changed after mixing fluorides into the Mg/NaNO3 compositions at a rate of 5% in excess of 100 %, and the formation of the magnesium fluoride may improve the agglomeration of the combustion prod?ucts.

Key words: applied chemistry , agglomeration , fluorides , burning rate

中图分类号: