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兵工学报 ›› 2013, Vol. 34 ›› Issue (6): 783-791.doi: 10.3969/j.issn.1000-1093.2013.06.020

• 综述 • 上一篇    下一篇

反应抑制球磨法制备超级铝热剂的研究进展

邹美帅, 杜旭杰, 李晓东, 杨荣杰   

  1. 北京理工大学材料学院, 北京100081
  • 上线日期:2013-08-27
  • 作者简介:邹美帅(1982—),男,讲师

Research Progress in Super Thermite Prepared by Arrested Reactive Milling

ZOU Mei-shuai, DU Xu-jie, LI Xiao-dong, YANG Rong-jie   

  1. School of Material Science and Engineering,Beijing Institute of Technology,Beijing 100081,China
  • Online:2013-08-27

摘要:

传统铝热剂具有较高的反应焓,但较慢的能量释放速率和较低的能量转化效率严重限制了其应用范围。超级铝热剂,即亚稳态分子间复合材料( MIC) 的出现,很好地解决了这一问题。在众多MIC 的制备方法中,反应抑制球磨(ARM)法优势明显。综述了ARM 法制备MIC 的最新研究进展,对现有的MIC 体系种类进行了总结,并分析了制备过程中工艺参数和环境条件对MIC 产物结构和性质(包括热性能、燃烧性能和力学性能) 的影响;指出了现有的MIC 球磨模型和燃烧模型的局限性,并对今后ARM 法制备MIC 的研究方向和研究重点进行了展望。

关键词: 材料合成与加工工艺, 反应抑制球磨法, 超级铝热剂, 亚稳态分子间复合材料, 反应活性

Abstract:

Traditional thermite has high enthalpy of reaction, but its slower energy releasing rate and lower energy transforming efficiency restrict its application fields. The appearance of super thermite, i. e. the metastable intermolecular composite(MIC), resolves this problem successfully. Compared with other preparation methods of MIC, the arrested reactive milling ( ARM) has many apparent advantages. Current progress in MIC prepared by ARM is reviewed. The kinds of MIC formulation up to now are summarized. The influence of processing parameters and ambient conditions on the structure and properties of MIC is analyzed systematically. The limitations of milling model and combustion model about MIC are pointed out. In addition, the future research direction and focus of MIC prepared by ARM are suggested.

Key words: meterials synthesis and processing technology, arrested reactive milling, super thermite, metastable intermolecular composite, reactivity

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