超临界CO2制备微孔球扁药的研究

doi:10.3969/j.issn.1000-1093.2012.05.004

兵工学报 ›› 2012, Vol. 33 ›› Issue (5): 534-539.doi: 10.3969/j.issn.1000-1093.2012.05.004

超临界CO₂制备微孔球扁药的研究

陈西如, 应三九, 肖正刚

(南京理工大学化工学院, 江苏南京 210094)

收稿日期:2011-06-02 修回日期:2011-06-02 上线日期:2014-03-04
作者简介:陈西如（1986—），男，硕士研究生

Research on Preparation of Microfoam Oblate Spherical Propellants by Supercritical CO₂

CHEN Xi-ru, YING San-jiu, XIAO Zheng-gang

(School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu, China)

Received:2011-06-02 Revised:2011-06-02 Online:2014-03-04

摘要/Abstract

摘要： 为改善球扁药的燃烧性能，根据燃面渐增原理，设计出了一种具有微孔结构的球扁药，并采用超临界流体技术升温发泡工艺制备出该结构的球扁药，分析了发泡过程中的泡孔的成核和长大机理；研究了CO₂含量和粒子对泡孔形貌的影响。扫描电镜(SEM）结果显示，微孔球扁药内部泡孔是独立的闭孔泡，粒子可以改变泡孔的形貌，随着CO₂在球扁药中含量的降低，平均泡孔直径变小。密闭爆发器试验表明，该微孔发射药具有良好的燃烧渐增性能。因此，利用超临界流体技术可以制备出不同泡孔形貌和燃烧性能的微孔球扁药。

关键词: 应用化学, 超临界CO₂, 微孔球扁药, 溶解度, 燃烧渐增性

Abstract: The microfoam oblate spherical propellants were designed and prepared in temperature-rising progress by supercritical fluids technique in order to improve their burning performance based on progressive burning surfaces theory and the mechanisms of foam nucleation and growth in the foaming progress were discussed. The effects of the contents of CO₂ and particles on foam morphology were investigated. Scanning electron microscope(SEM) results showed that foams in microfoam oblate spherical propellants were closed and isolated, foam morphology can be changed by particle and the mean foam diameter became small as the contents of CO₂ in oblate spherical propellants decreasing. The closed bomb tests indicated that these microfoam oblate spherical propellants showed progressive burning performance. Therefore the microfoam oblate spherical propellants with different foam morphology and burning performance can be achieved by supercritical fluids technique.

Key words: applied chemistry, supercritical CO₂, microfoam oblate spherical propellants, solubility, progressive combustion

中图分类号:

TQ562

陈西如, 应三九, 肖正刚. 超临界CO₂制备微孔球扁药的研究[J]. 兵工学报, 2012, 33(5): 534-539.

CHEN Xi-ru, YING San-jiu, XIAO Zheng-gang. Research on Preparation of Microfoam Oblate Spherical Propellants by Supercritical CO₂[J]. Acta Armamentarii, 2012, 33(5): 534-539.

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超临界CO₂制备微孔球扁药的研究

Research on Preparation of Microfoam Oblate Spherical Propellants by Supercritical CO₂

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