1.北京理工大学 爆炸科学与安全防护全国重点实验室, 北京 100081
2.重庆红宇精密工业集团有限公司, 重庆 4027604
邮箱: bityanshi@126.com
收稿:2026-04-13,
修回:2026-05-20,
录用:2026-05-25,
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姚杰, 闫石, 徐一龙, 等. Al-Li合金燃料/CL-20浇注炸药的反应特性及安全性能[J/OL]. 兵工学报, 2026.
YAO Jie, YAN Shi, XU Yilong, et al. Study on the Reaction Characteristics and Safety Performance of Al-Li Alloy Fuel/CL-20 Cast Explosive[J/OL]. Acta Armamentarii, 2026.
姚杰, 闫石, 徐一龙, 等. Al-Li合金燃料/CL-20浇注炸药的反应特性及安全性能[J/OL]. 兵工学报, 2026. DOI: 10.12382/bgxb.2026.0327.
YAO Jie, YAN Shi, XU Yilong, et al. Study on the Reaction Characteristics and Safety Performance of Al-Li Alloy Fuel/CL-20 Cast Explosive[J/OL]. Acta Armamentarii, 2026. DOI: 10.12382/bgxb.2026.0327.
为显著提升浇注炸药的能量输出与综合毁伤效能,本研究聚焦于Al-Li合金燃料在高能炸药体系中的应用潜力与作用机制。利用真空熔炼-气流雾化复合制备技术,成功定制了粒径为13 µm Al-Li合金燃料。借助激光诊断、电爆炸试验、相容性试验及爆热测试等手段,系统研究了该合金燃料与CL-20之间的反应特性,及其在CL-20基浇注炸药中的安全性与爆轰性能。结果表明:制备的Al-Li合金燃料粒度均匀、表面光滑,中位粒径(
D
50
)约为13 µm。随着锂含量增加至4%,燃料的硬度逐渐上升,燃烧热值提升至31.03 kJ/g,与CL-20之间的反应特性更加显著。瞬态升温特性表明,Al-Li合金燃料在瞬时升温过程中的增压速率和冲击波速度均显著提升,其中AlLi4合金燃料的增压速率可达24.39 MPa·s
-1
,冲击波速度可达607.73 m/s。Al-Li合金燃料与浇注炸药关键组分HTPB之间的相容性较差,当锂含量提升至4%时,相容性已无法满足使用要求;同时,机械感度亦随锂含量的增加逐渐升高。此外,设计了含AlLi2浇注炸药,与含铝浇注炸药相比,其爆速提升123.68 m/s,爆热提升240.56 kJ/kg。
To significantly enhance the energy output and comprehensive damage efficacy of cast explosives
this study focuses on the application potential and action mechanism of Al-Li alloy fuel in high-energy explosive systems. Al-Li alloy fuel with a particle size of 13 µm was successfully customized using a combined vacuum melting and gas atomization preparation technique. The reaction characteristics between the alloy fuel and CL-20
as well as its safety and detonation performance in CL-20‑based cast explosives
were systematically investigated by means of laser diagnostics
electric explosion tests
compatibility tests
and detonation heat measurements. The results show that the as-prepared Al-Li alloy fuel exhibits uniform particle size and a smooth surface
with a median particle diameter (
D
50
) of approximately 13 µm. As the l
ithium content increases to 4%
the hardness of the fuel gradually rises
the combustion heat value increases to 31.03 kJ/g
and the reaction characteristics with CL-20 become more pronounced. Transient heating characteristics indicate that the pressurization rate and shock wave velocity of the Al-Li alloy fuel during instantaneous temperature rise are significantly improved. Specifically
for the AlLi4 alloy fuel
the pressurization rate reaches 24.39 MPa·s⁻¹
and the shock wave velocity reaches 607.73 m/s. The compatibility between the Al-Li alloy fuel and HTPB
a key component of the cast explosive
is poor; when the lithium content increases to 4%
the compatibility no longer meets the application requirements. Meanwhile
the mechanical sensitivity gradually increases with rising lithium content. Furthermore
compared with an aluminum‑containing cast explosive
the cast explosive containing AlLi2 exhibits an increase in detonation velocity of 123.68 m/s and an increase in detonation heat of 240.56 kJ/kg.
LIU W J , BAI C , LIU Q M , et al . Effect of metal dust fuel at a low concentration on explosive/air explosion characteristics [J ] . Combustion and Flame , 2020 , 221 : 41 - 49 .
王子 , 张鹏程 , 林秋汉 , 等 . 含金属混合炸药的发展与展望 [J ] . 兵器装备工程学报 , 2025 , 46 ( 06 ): 333 - 343 .
WANG Z , ZHANG P C , LIN Q H , et al . Development and application of metal‑containing mixed explosives [J ] . Journal of Ordnance Equipment Engineering , 2025 , 46 ( 6 ): 333 - 343 . (in Chinese)
胡宏伟 , 宋浦 , 邓国强 , 等 . 温压炸药的特性及发展现状 [J ] . 力学进展 , 2022 , 52 ( 01 ): 53 - 78 .
HU H W , SONG P , DENG G Q , et al . Characteristics and development status of thermobaric explosives [J ] . Advances in Mechanics , 2022 , 52 ( 1 ): 53 - 78 . (in Chinese)
王伯良 . 燃料空气炸药发展趋势分析 [J ] . 含能材料 , 2024 , 32 ( 12 ): 1257 - 1259 .
WANG B L . Analysis of development trends of fuel‑air explosives [J ] . Energetic Materials , 2024 , 32 ( 12 ): 1257 - 1259 . (in Chinese)
GUO H L , ZHANG W P , PANG W Q . Preparation Technology, Reactivity and Applications of Nano-Aluminum in Explosives and Propellants: A Review [J ] . Nanomaterials , 2025 , 15 ( 20 ), 1564 - 1599 .
GUO Y , TAN K Y , LIU H H , et al . Incorporating fluoropolymer-coated micron-sized aluminum with enhanced reactivity into aluminized explosives to improve their detonation performance [J ] . Energetic Materials Frontiers , 2023 , 4 ( 1 ), 103 - 109 .
YAN Z X . Compare study on the explosion characteristics of nano-aluminum and micro-aluminum [J ] . Acta Physica Sinica , 2011 , 60 ( 7 ), 076202 .
ALY Y , SCHOENITZ M , DREIZIN E L . Ignition and combustion of mechanically alloyed Al–Mg powders with customized particle sizes [J ] . Combustion and Flame , 2013 , 160 ( 4 ): 835 - 842 .
FENG Y C , MA L K , XIA Z X , et al . Ignition and combustion characteristics of single gas-atomized Al–Mg alloy particles in oxidizing gas flow [J ] . Energy , 2020 , 196 : 117036 .
ZHU Y L , LE W , ZHAO W J , et al . Promising fuels for energetics: Spherical Al-Li powders with high reactivity via incorporation of Li [J ] . Fuel , 2022 , 323 : 124393 .
XU D H , LI S J , HUANG X F , et al . Enhancement effect of Li addition on nitriding reaction and combustion of Al-Li alloy in N 2 [J ] . Fuel , 2024 , 361 : 130774 .
LIANG D L , XIAO R , LIU J Z , et al . Ignition and heterogeneous combustion of aluminum boride and boron–aluminum blend [J ] . Aerospace Science and Technology , 2019 , 84 : 1081 - 1091 .
KOROTKIKH A G , SOROKIN I V . Effect of Boron on the Combustion Parameters of Hem and Oxidation of Al/B and Ti/B Nanopowders [J ] . Russian Physics Journal , 2021 , 64 ( 4 ): 567 - 573 .
FENG Y C , HUANG G S , LUO J L et al . Experimental Investigation on ignition and Micro-Explosion combustion characteristics of single Al–Li alloy particles in High-Temperature gas environments [J ] . Fuel , 2026 , 408 : 137666 .
YAO H H , LI S J , HUANG H Y , et al . Identification of alloying Li effect on ignition and combustion of Al fuel in water vapor atmosphere [J ] . Chemical Engineering Journal , 2025 , 519 : 164969 .
Terry B C , Gunduz I E , Pfeil M A , et al . A mechanism for shattering microexplosions and dispersive boiling phenomena in aluminum-lithium alloy based solid propellant [J ] . Proceedings of the Combustion Institute , 2017 , 36 ( 2 ): 2309 - 2316 .
Ruesch M , Son S F , Goldenstein C S . Characterization of aluminum-lithium composite-propellant flames via laser absorption spectroscopy [C ] // AIAA Scitech 2021 Forum . 2021 : 1969 .
Zhou X , Huang L , Liu X F , et al . Combustion characteristics of Al-Li alloy powder and its application in solid propellant [J ] . Journal of Physics: Conference Series , 2023 , 2478 ( 3 ): 032067 .
Xiong W Q , Liu Y J , Zhang T F , et al . Effect of Al-Li Alloy on the Combustion Performance of AP/RDX/Al/HTPB Propellant [J ] . Aerospace , 2023 , 10 ( 3 ): 222 .
Yao J , Chang K H , Yang F Y , et al . Energy output characteristics of an enhanced aluminized explosive: Impact of Al-Li alloy fuel [J ] . Combustion and Flame , 2025 , 275 : 114064 .
YAO J , YAN S , LIU J H , et al . Reaction characteristics of Al–Mg alloy fuels with heterogeneous oxidation shell structures [J ] . Chemical Engineering Journal , 2024 , 495 : 153384 .
吴亚琛 , 沈忱 , 孙晓乐 , 等 . 浇注六硝基六氮杂异伍兹烷基混合炸药驱动性能 [J ] . 兵工学报 , 2020 , 41 ( 12 ): 2458 - 2465 .
WU Y C , SHEN C , SUN X L , et al . Driving performance of cast hexanitrohexaazaisowurtzitane-based composite explosive [J ] . Acta Armamentarii , 2020 , 41 ( 12 ): 2458 - 2465 . (in Chinese)
王万军 , 孙秀娟 , 张雷 等 . 亚微秒内金丝电爆炸的激光探针测试及三维动力学仿真 [J ] , 含能材料 , 2019 , 27 ( 6 ): 473 - 480 .
WANG W J , SUN X J , ZHANG L , et al . Laser probe test and three-dimensional dynamic simulation of gold wire electrical explosion in sub-microseconds [J ] , Energetic Materials , 2019 , 27 ( 6 ): 473 - 480 .
Nie J X , Kan R Z , Jiao Q J , et al . Studies on aluminum powder combustion in detonation environment [J ] . Chinese Physics B , 2022 , 31 ( 4 ): 44703 - 044703 .
HUANG R K , HU A B , ZHU Y C , et al . Research on the energy properties and the storage stability of Al–Si–Li ternary alloy powders [J ] . Journal of Materials Research and Technology , 2024 , 28 : 4805 - 4814 .
周正青 , 杜泽晨 , 蒋慧 , 等 . 铝含量对TNT/Al炸药爆轰反应区结构的影响 [J ] . 南京理工大学学报 , 2022 , 46 ( 5 ): 523 - 528 .
ZHOU Z Q , DU Z C , JIANG H , et al . Effect of aluminum content on detonation reaction zone structure of TNT/Al explosive [J ] . Journal of Nanjing University of Science and Technology , 2022 , 46 ( 5 ): 523 - 528 . (in Chinese)
杜明燃 , 汪旭光 , 郭子如 , 等 . 爆轰产物组成和爆轰参数计算方法的理论研究 [J ] . 爆炸与冲击 , 2015 , 35 ( 4 ): 449 - 453 .
DU M R , WANG X G , GUO Z R , et al . Theoretical study on the composition of detonation products and the calculation method of detonation parameters [J ] . Explosion and Shock , 2015 , 35 ( 4 ): 449 - 453 .
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