北京理工大学 爆炸科学与安全防护全国重点实验室, 北京 100081
*gechao@bit.edu.cn
收稿:2024-10-11,
网络出版:2025-08-28,
纸质出版:2025-08-31
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闫月光, 葛超, 张勇, 等. 基于弱耦合跨尺度方法的氟聚物基活性材料冲击力-化学响应行为[J]. 兵工学报, 2025,46(8):240948.
Yueguang YAN, Chao GE, Yong ZHANG, et al. Mechanochemical Response of Fluoropolymer-matrix Reactive Materials Subjected to Shock Loading Based on Weak Coupling Trans-scale Method[J]. Acta Armamentarii, 2025, 46(8): 240948.
闫月光, 葛超, 张勇, 等. 基于弱耦合跨尺度方法的氟聚物基活性材料冲击力-化学响应行为[J]. 兵工学报, 2025,46(8):240948. DOI: 10.12382/bgxb.2024.0948.
Yueguang YAN, Chao GE, Yong ZHANG, et al. Mechanochemical Response of Fluoropolymer-matrix Reactive Materials Subjected to Shock Loading Based on Weak Coupling Trans-scale Method[J]. Acta Armamentarii, 2025, 46(8): 240948. DOI: 10.12382/bgxb.2024.0948.
为了研究PTFE/Al/W氟聚物基活性材料冲击加载下的力-化学响应行为
开展氟聚物基活性材料落重冲击试验
提出弱耦合跨尺度数值计算方法
基于此方法建立宏观-细观氟聚物基活性材料落重冲击加载反应过程的跨尺度数值仿真模型。结合跨尺度数值仿真对落重冲击试验的宏观、细观结构力化响应行为及冲击激活机理进行讨论分析。分析结果表明:W含量对氟聚物基活性材料冲击激活反应影响显著
随着W含量增加
材料体系冲击激活阈值降低;弱耦合跨尺度数值仿真分析模型有效模拟了氟聚物基活性材料的力-化学响应过程;X型剪切带是氟聚物基活性材料破碎、激活引发反应的主要机制
其形成、演化和分布受W含量影响较大。
In order to study the mechanochemical response behavior of PTFE/Al/W fluoropolymer-matrix reactive materials under shock loading
the drop-weight impact test of fluoropolymer-matrix reactive materials is carried out
and a weak coupling trans-scale numerical calculation method is proposed.Based on this method
a trans-scale numerical simulation model is established for the drop-weight impact loading reaction process of macro-meso scale fluoropolymer-matrix reactive material.The mechanochemical response behaviors and impact activation mechanisms of macroscopic and mesoscopic structures of sample in the drop-weight impact test are discussed and analyzed through trans-scale numerical simulation.The results show that the content of W has a significant effect on the impact activation reaction of fluoropolymer-matrix reactive materials
and the impact activation threshold of the reactive materials system decreases with the increase of W content.The weak coupling trans-scale numerical simulation analysis model effectively simulates the mechanochemical response process of fluoropolymer-matrix reactive materials.The X-shaped shear band is the dominant mechanism for the breakage and activation of fluoropolymer-matrix reactive materials
and its formation
evolution and distribution are greatly affected by W content.
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任会兰 , 李尉 , 刘晓俊 , 等 . 钨颗粒增强铝/聚四氟乙烯材料的冲击反应特性 [J ] . 兵工学报 , 2016 , 37 ( 5 ): 872 - 878 . DOI: 10.3969/j.issn.1000-1093.2016.05.014 http://doi.org/10.3969/j.issn.1000-1093.2016.05.014 针对模压烧结法制备的4种不同配比的铝/钨/聚四氟乙烯(Al/W/PTFE)反应材料,采用分离式霍普金森压杆加载方法和高速摄影技术研究其冲击反应特性。实验结果表明:随着W含量的增加,反应材料的屈服强度和破坏强度提高;反应材料的应力-应变曲线分为弹性阶段、硬化阶段和破坏阶段,动态压缩特性具有明显的应变率效应;Al/W/PTFE反应材料的冲击反应过程可分为变形、破坏和燃烧反应;Al/W/PTFE反应材料中增加W含量,提高了材料的反应应变率阈值和比能量阈值。
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HU R , JIANG C L , MAO L , et al . Effect of Al particle size on the shock-induced reaction characteristics of Al-rich PTFE/Al composites [J ] . Acta Armamentarii , 2022 , 43 ( 1 ): 48 - 56 . (in Chinese) DOI: 10.3969/j.issn.1000-1093.2022.01.006 http://doi.org/10.3969/j.issn.1000-1093.2022.01.006 The effect of Al particle size on the shock-induced reaction characteristics of PTFE/Al reactive material with a mass ratio of 50∶50 is investigated. 4 kinds of PTFE/Al reactive material specimens with different Al particle sizes were prepared by molding and sintering. The reactive material specimens were tested by using split-Hopkinson pressure bar (SHPB), and the shock-induced reaction processes of PTFE/Al reactive material at different strain rates were recorded with a high-speed camera. The results show that, as the Al particle size increases from 50 nm to 10 μm, the reaction delay rises up to 40% and the reaction duration decreases up to 17%, while the amount of reactive material participating in the reaction decreases, and the reaction intensity and energy release decrease. When the Al particle size increases to 70 μm, it is difficult to ignite under SHPB loading. The strain rate also greatly influences the reactive characteristics of reactive material,and the reaction delay of PTFE/Al reactive material decreases with the increase in the loading strain rate. The results show that Al particle size greatly influences the impact reaction diffusion, reaction speed, and extent of reaction of PTFE/Al reactive material, and its impact reaction property can be adjusted by adjusting Al particle size.
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