1. 南京理工大学 化学与化工学院, 江苏 南京 210094
2. 北京化工大学 化学工程学院, 北京 100029
3. 上海航天动力技术研究所, 浙江 湖州 313000
4. 广西大学 发展规划处, 广西 南宁 530004
*邮箱: zhangxr@mail.buct.edu.cn
收稿:2023-07-23,
网络出版:2024-10-30,
纸质出版:2024-10-31
移动端阅览
沈业炜, 邢书敏, 杨茂发, 等. 基于幂律方程的PBT/A3/AP体系抗拉强度分析[J]. 兵工学报, 2024,45(10):3530-3537.
Yewei SHEN, Shumin XING, Maofa YANG, et al. Analysis of Tensile Strength of PBT/A3/AP System Based on Power Law Equation[J]. Acta Armamentarii, 2024, 45(10): 3530-3537.
沈业炜, 邢书敏, 杨茂发, 等. 基于幂律方程的PBT/A3/AP体系抗拉强度分析[J]. 兵工学报, 2024,45(10):3530-3537. DOI: 10.12382/bgxb.2023.0686.
Yewei SHEN, Shumin XING, Maofa YANG, et al. Analysis of Tensile Strength of PBT/A3/AP System Based on Power Law Equation[J]. Acta Armamentarii, 2024, 45(10): 3530-3537. DOI: 10.12382/bgxb.2023.0686.
为解决3
3-双(叠氮甲基)氧杂环丁烷/四氢呋喃共聚醚(Poly(3
3'-Bis(azidomethyl)oxetane-co-Tetrahydrofuran)
PBT)固体推进剂力学性能预估难的问题
分析PBT/双(2
2-二硝基丙醇)缩乙醛/双(2
2-二硝基丙醇)缩甲醛等质量比混合物(A3)/高氯酸铵(Ammonium Perchlorate
AP)体系的拉伸断裂行为
建立描述该体系抗拉强度的幂律方程
并获得界面相、分散相、连续相对抗拉强度的影响规律。实验结果表明:随着氧化剂粒径减小
体积分数增加
推进剂弹性模量、抗拉强度均升高。界面相作用对推进剂抗拉强度起主导作用
数值上与
<math id="Mml1"> <msubsup> <mrow> <mi>v</mi></mrow> <mrow> <mi mathvariant="normal">f</mi></mrow> <mrow> <mn>2</mn></mrow></msubsup></math>
/
r
(
v
f
为体积分数
r
为氧化剂粒径)正相关。当氧化剂粒径小于100μm时
界面相的主导作用越发明显。分散相的作用随着氧化剂粒径的增大而增大
数值上与
v
f
r
5
正相关。当粒径大于100μm时
分散相的作用开始变得明显;当粒径大于150μm时
分散相的作用已经接近界面相的作用
这时颗粒间的相互作用不可忽略。相对而言
连续相对推进剂抗拉强度的贡献较小
数值上与(1-
v
f
)
5
正相关
与界面相相比几乎可以忽略不计。建立的PBT/A3/AP体系抗拉强度幂律方程拟合结果与实验结果吻合度高(
R
2
>
0.99)
可以为推进剂配方设计提供理论指导
缩短推进剂配方研制周期
降低人力和物力成本。
In order to solve the difficulty in predicting the mechanical properties of poly(3
3'-bis(azidomethyl)oxetane-co-tetrahydrofuran) (PBT) solid propellant
the tensile fracture behavior of PBT/A3/AP system is analyzed. A power law equation describing the tensile strength of the system is established. The influence rules of interfacial phase
dispersed phase and continuous phase on tensile strength were obtained. The results show that the elastic modulus and tensile strength of propellant increase with the decrease in oxidant particle size and the increase in volume fraction. The influence of interfacial phase interaction on the tensile strength of propellant is dominant
which is positively correlated with
<math id="Mml2"> <msubsup> <mrow> <mi>v</mi></mrow> <mrow> <mi mathvariant="normal">f</mi></mrow> <mrow> <mn>2</mn></mrow></msubsup></math>
/
r
(
v
f
: volume fraction
r
: oxidant particle size). When the oxidant particle size is less than 100μm
the dominant role of interfacial phase becomes more obvious. The effect of dispersed phase increases with the increase in oxidant particle size. The value is positively correlated with
v
f
r
5
. When the particle size is larger than 100μm
the effect of dispersed phase becomes apparent. When the particle size is larger than 150μm
the effect of dispersed phase approaches that of the interfacial phase. In this case
the interaction between particles cannot
be ignored. The continuous phase has little influence on the tensile strength of propellant. The value is positively correlated with (1-
v
f
)
5
. Compared with the interface phase
the effect of continuous phase is almost negligible. The fitting results of the power law equation for the tensile strength of PBT solid propellant are in good agreement with the experimental results(
R
2
>
0.99). The calculated results can be used as reference for propellant formulation design
thereby reducing the development cycle while simultaneously lowering the costs in terms of manpower and resources.
庞爱民 , 黎小平 . 固体推进剂技术的创新与发展规律 [J ] . 含能材料 , 2015 , 23 ( 1 ): 3 - 6 .
PANG A M , LI X P . Invovation and development laws of solid propellant technology [J ] . Chinese Journal of Energetic Materials , 2015 , 23 ( 1 ): 3 - 6 . (in Chinese)
吴战武 , 刘旭峰 , 纪明卫 , 等 . 少烟PBT推进剂制备及性能研究 [J ] . 爆破器材 , 2019 , 48 ( 4 ): 17 - 22 .
WU Z W , LIU X F , JI M W , et al . Preparation and properties of reduced smoke PBT propellant [J ] . Explosive Materials , 2019 , 48 ( 4 ): 17 - 22 . (in Chinese)
李苗苗 , 陈静静 , 郑亭亭 , 等 . HTPE与PBT对推进剂慢速烤燃特性的影响 [J ] . 兵器装备工程学报 , 2022 , 43 ( 6 ): 13 - 18 .
LI M M , CHEN J J , ZHENG T T , et al . Effect of HTPE and PBT binders on slow cook-off characteristics of propellant [J ] . Journal of Ordnance Equipment Engineering , 2022 , 43 ( 6 ): 13 - 18 . (in Chinese)
王旭 , 徐森 , 李苗苗 , 等 . 钝感氧化剂对PBT基推进剂低易损性的影响 [J ] . 兵器装备工程学报 , 2022 , 43 ( 6 ): 7 - 12 , 18.
WANG X , XU S , LI M M , et al . Influence of insensitive oxidants on low vulnerability of PBT-based propellants [J ] . Journal of Ordnance Equipment Engineering , 2022 , 43 ( 6 ): 7 - 12 , 18. (in Chinese)
LÓPEZ R , ORTEGA DE LA ROSA A , SALAZAR A , et al . Structural integrity of aged hydroxyl-terminated polybutadiene solid rocket propellant [J ] . Journal of Propulsion and Power , 2018 , 34 ( 1 ): 75 - 84 .
TEJAS NIKAM , MRUNAL PARDESHI , AMIT PATIL , et al . Structural integrity analysis of propellant in solid rocket motor [C ] // Proceedings of International Conference on Ideas, Impact and Innovation in Mechanical Engineering (ICIIIME 2017). Vadgao , India : International Journal on Recent and Innovation Trends in Computing and Communication , 2017 , 5 ( 6 ): 896 - 902 .
ZHOU D M , LIU X Y , SUI X , et a1. Accelerated aging and structural integrity analysis approach to predict the service life of solid rocket motors [C ] // Proceedings of the 51st AIAA/SAE/ASEE Joint Propulsion Conference. Orlando, FL , US : AIAA , 2015 : 1 - 8 .
胡义文 , 左海丽 , 郑启龙 , 等 . PBT基复合固体推进剂高温蠕变行为研究 [J ] . 固体火箭技术 , 2018 , 41 ( 1 ): 41 - 46 .
HU Y W , ZUO H L , ZHENG Q L , et al . Creep behavior of composite solid propellant based on PBT at high temperature [J ] . Journal of Solid Rocket Technology , 2018 , 41 ( 1 ): 41 - 46 . (in Chinese)
张哲 , 曾国伟 , 张正金 , 等 . PBT 固体推进剂低温力学性能研究 [J ] . 推进技术 , 2022 , 43 ( 9 ): 384 - 390 .
ZHANG Z , ZENG G W , ZHANG Z J , et al . Low temperature mechanical properties of PBT solid propellant [J ] . Journal of Propulsion Technology , 2022 , 43 ( 9 ): 384 - 390 . (in Chinese)
沈业炜 , 仉玉成 , 童丽伦 . 中性键合剂在叠氮高能推进剂中应用工艺研究 [J ] . 上海航天 , 2017 , 34 ( 6 ): 90 - 95 .
SHEN Y W , ZHANG Y C , TONG L L . Study on application process of neutral polymeric bonding agent in high energy nitrine propellant [J ] . Aerospace Shanghai , 2017 , 34 ( 6 ): 90 - 95 . (in Chinese)
宋琴 , 王艳萍 , 廖菊平 , 等 . 叠氮微烟推进剂宽温域力学性能研究 [J ] . 火炸药学报 , 2021 , 44 ( 4 ): 521 - 525 . DOI: 10.14077/j.issn.1007-7812.202102006 http://doi.org/10.14077/j.issn.1007-7812.202102006 为研究战斗部壳体破片平均质量与平均穿孔面积的关系,针对3种战斗部装药JH-2、JOXL-1、RBOE-1设计了战斗部静爆试验和水井回收试验。应用图像处理技术,利用侵彻孔洞图像轮廓信息和自然破片平均质量的关系,标定了3种炸药的破片平均质量比例系数。结果表明,当壳体破片质量大于0.1g的破片计入有效破片时,3种炸药的破片平均质量比例系数分别为0.2249、0.3010、0.3907; 当壳体破片质量大于1g的破片计入有效破片时,3种炸药的破片平均质量比例系数分别为0.5521、0.5772、1.0646; 通过战斗部静爆后自然破片的穿靶试验可获得战斗部壳体形成自然破片的平均质量,较大程度地减少了以往试验的复杂性,方便在实际工程中应用,可为常规战斗部乃至不敏感战斗部的毁伤效能评估研究提供一种新的技术途径。
SONG Q , WANG Y P , LIAO J P , et al . Research on the mechanical property of azide low smoke propellant at broad temperature range [J ] . Chinese Journal of Explosives & Propellants , 2021 , 44 ( 4 ): 521 - 525 . (in Chinese)
谢五喜 , 赵昱 , 刘运飞 , 等 . 3,3-二叠氮甲基氧丁环-四氢呋喃共聚醚推进剂的力学性能影响因素 [J ] . 化工新型材料 , 2020 , 48 ( 2 ): 163 - 165 , 172. 采用力学性能测试和扫描电镜等手段研究了不同网络调节剂、固化剂和键合剂对3,3-二叠氮甲基氧丁环-四氢呋喃共聚醚 (BAMO-THF)推进剂力学性能的影响。结果表明:网络调节剂三羟甲基丙烷使推进剂高温50℃和常温25℃强度提高到0.318MPa和0.358MPa;固化剂的异氰酸酯使推进剂高温和常温强度提高到0.656MPa和0.734MPa;组合键合剂N和T使BAMO-THF推进剂的高温、低温和常温强度分别达到0.653MPa、2.228MPa和0.693MPa,延伸率分别为47.0%、62.1%和42.3%。
XIE W X , ZHAO Y , LIU Y F , et al . Influence factor for mechanical property of azido-typed BAMO-THF propellant [J ] . New Chemical Materials , 2020 , 48 ( 2 ): 163 - 165 , 172. (in Chinese) In order to improve the mechanical properties of BAMO-THF propellants,the effect of crosslinkers,curing agents and bonding agents on the BAMO-THF propellants of was investigated.The resluts indicated that:the tensile stress of the matrixes with the crosslinker TMP increased to 0.318MPa and 0.358MPa at 50℃ and 25℃,respectivelly.The tensile stress of the matrixes with the curing agent N-100 increased to 0.656MPa and 0.734MPa at 50℃ and 25℃,respectivelly.The tensile stress of the matrixes with bonding agent N and T reached 0.653MPa,2.228MPa and 0.693MPa at high,low and room temperature,respectivelly,meanwhile the corresponding tensile elongation reached 47.0%,62.1% and 42.3%.
赵菲 , 孙学红 , 郝立新 , 等 . 聚氨酯弹性体的力学性能影响因素研究 [J ] . 聚氨酯工业 , 2001 , 16 ( 1 ): 9 - 11 .
ZHAO F , SUN X H , HAO L X , et al . Study on the factors influencing mechanical properties of polyurethane elastomers [J ] . Polyurethane Industry , 2001 , 16 ( 1 ): 9 - 11 . (in Chinese)
WUBULIAISAN M , WU Y Q , HOU X , et al . A viscoelastic constitutive model considering deformation and environmental- induced damages for solid propellants [J ] . Aerospace Science and Technology , 2023 , 132 : 108055 .
ZHANG H N , CHANG H , LI X J , et al . The effect of strain rate on compressive behavior and failure mechanism of CMDB propellant [J ] . Defence Technology , 2022 , 18 ( 3 ): 467 - 475 . DOI: 10.1016/j.dt.2021.02.007 http://doi.org/10.1016/j.dt.2021.02.007 The compressive mechanical behavior of composite modified double base (CMDB) propellant was investigated across a wide scope of strain rates ranging from 10−3 s−1 to 4210 s−1 at room temperature, by applying a conventional universal testing machine and a split Hopkinson tension bar (SHPB), respectively. The derived stress-strain curves at different strain rates show a strong rate dependence, indicated that yield stress, ultimate stress and strain energy density of CMDB propellant all increase with strain rate by following a power law function, while the amplification of increase are different. The deformation and damage modes of CMDB propellant has changed from a typical ductile manner (cracking along the axial direction) to a brittle manner (maximum shear failure) with increasing of strain rate. Scanning electron microscopy (SEM) was employed to explore the microscopic failure characteristics of CMDB propellant. Under quasi-static loading, the nearly parallel micro-cracks propagating along the axial direction and the debonding of RDX particle without particle crushing can be observed. While under dynamic loading, the micro-crack is 45° angle to the axial direction, and multiple cracking modes of RDX particles appeared. Finally, the correlation between strain energy density and failure mechanisms of CMDB propellant was revealed by developing four characteristic failure modes. The findings of this study is very important to evaluate the structural integrity of CMDB propellant. © 2021 China Ordnance Society
张镇国 , 何景轩 , 沙宝林 , 等 . 丁羟基固体推进剂的破坏包络及其演化行为研究 [J ] . 宇航学报 , 2021 , 42 ( 12 ): 1571 - 1578 .
ZHANG Z G , HE J X , SHA B L , et al . A study on failure envelopes of HTPB solid propellant and their evolution [J ] . Journal of Astronautics , 2021 , 42 ( 12 ): 1571 - 1578 . (in Chinese)
张炜 . 基于材料基因工程的复合固体推进剂力学性能预估方法 [J ] . 含能材料 , 2019 , 27 ( 4 ): 270 - 273 .
ZHANG W . Mechanical property prediction for composite solid propellants based on genetic engineering of materials [J ] . Chinese Journal of Energetic Materials , 2019 , 27 ( 4 ): 270 - 273 . (in Chinese)
张高章 , 司马凯 . 复合固体推进剂力学性能的建模预测研究 [J ] . 化工新型材料 , 2018 , 46 ( 12 ): 160 - 164 . 首次将反向传输(BP)神经网络模型和经遗传算法(GA)优化后的BP(GA-BP)网络模型应用于研究多种工艺助剂和不同测试温度对复合固体推进剂力学性能的影响。结果表明:所建模型对复合固体推进剂力学性能均具有一定的预测能力,通过对未参与建模的5组数据的预测计算,GA-BP模型的抗拉强度预测的平均相对误差由BP模型的15.66%降低至12.86%,断裂伸长率由BP模型的11.24%降低至3.9%,预测精度得到了提高。
ZHANG G Z , SIMA K . Modeling and prediction of mechanical property of composite solid propellant [J ] . New Chemical Materials , 2018 , 46 ( 12 ): 160 - 164 . (in Chinese) For the first time,the back propagation neural network(BP neural network) model and BP network model optimized by genetic algorithm (GA) were applied to study the effects of various processing aids and different test temperatures on the mechanical properties of composite solid propellant.The results showed that the model had a certain ability to predict the mechanical performance of composite solid propellant.Through the prediction of five groups of data that did not participate in the modeling calculation,it was found that the average relative error of tensile strength of prediction of BP model before and after the optimization of GA decreased from 15.66% to 12.86%,their elongation at break decreased from 11.24% to 3.9%,the prediction precision was improved.
INGLIS H M . Modeling the effect of debonding on the constitutive response of heterogeneous materials [D ] . Champaign, IL, US : University of Illinois at Urbana-Champaign , 2014 .
胡应杰 , 陈昌云 , 陈凯 . 单基和双基发射药力学性能的MD模拟研究 [J ] . 南京晓庄学院学报 , 2007 ( 6 ): 47 - 50 .
HU Y J , CHEN C Y , CHEN K . Molecular dynamics simulation of mechanical properties of single-base and double-base propellants [J ] . Journal of Nanjing Xiaozhuang University , 2007 ( 6 ): 47 - 50 . (in Chinese)
王鸿丽 , 许进升 , 刘宗魁 , 等 . 复合改性双基推进剂黏弹性-黏塑性-黏损伤本构模型研究 [J ] . 兵工学报 , 2018 , 39 ( 7 ): 1308 - 1315 . DOI: 10.3969/j.issn.1000-1093.2018.07.008 http://doi.org/10.3969/j.issn.1000-1093.2018.07.008 为描述复合改性双基(CMDB)推进剂复杂的力学性能,推导出黏弹性-黏塑性-黏损伤本构模型。进行一系列蠕变-回复试验,获得了本构模型参数。通过不同应力水平和不同加载时间下的蠕变-回复试验和恒加载率-回复试验,验证了本构模型的有效性。结果表明:黏弹性-黏塑性-黏损伤本构模型能够预测CMDB推进剂的蠕变-回复响应和恒加载率-回复响应;与黏弹性-黏塑性本构模型相比,黏弹性-黏塑性-黏损伤模型对CMDB推进剂力学性能的预测能力明显提高;损伤变量随着应变增大,在经过缓慢增大和快速增大后逐渐趋于稳定,应变变化越慢,损伤变量越大,黏弹性-黏塑性-黏损伤模型和黏弹性-黏塑性模型的预测结果差别就越大。
WANG H L , XU J S , LIU Z K , et al . Research on the Viscoelasticity-viscoplasticity-viscodamage constitutive model of composite modified double base propellant [J ] . Acta Armamentarii , 2018 , 39 ( 7 ): 1308 - 1315 . (in Chinese)
田德余 , 洪伟良 , 刘剑洪 , 等 . 丁羟固体推进剂力学性能模拟计算 [J ] . 推进技术 , 2008 , 29 ( 1 ): 114 - 118 .
TIAN D Y , HONG W L , LIU J H , et al . Modeling for mechanical properties of HTPB solid propellants [J ] . Journal of Propulsion Technology , 2008 , 29 ( 1 ): 114 - 118 . (in Chinese)
贵大勇 , 刘剑洪 , 田德余 , 等 . NEPE高能推进剂力学性能模拟计算 [J ] . 推进技术 , 2010 , 31 ( 4 ): 63 - 66 ,70.
GUI D Y , LIU J H , TIAN D Y , et al . Modeling of mechanical properties of NEPE high energetic propellants [J ] . Journal of Propulsion Technology , 2010 , 31 ( 4 ): 63 - 66 ,70. (in Chinese)
沈业炜 , 仉玉成 , 童丽伦 . PBT钝感高能推进剂高温力学性能调节技术研究 [J ] . 推进技术 , 2018 , 39 ( 11 ): 2595 - 2600 .
SHEN Y W , ZHANG Y C , TONG L L . Study on adjustment technology for high temperature mechanical properties of PBT insensitive high energy propellant [J ] . Journal of Propulsion Technology , 2018 , 39 ( 11 ): 2595 - 2600 . (in Chinese)
张涛 . Al粉对推进剂力学性能的影响 [J ] . 化学推进剂与高分子材料 , 2023 , 21 ( 5 ): 54 - 57 .
ZHANG T . Influence of Al power on mechanical performance of propellant [J ] . Chemical Propellants & Polymeric Materials , 2023 , 21 ( 5 ): 54 - 57 . (in Chinese)
袁申 , 刘海青 , 齐铭 , 等 . 复合推进剂力学性能及其改善技术研究进展 [J ] . 兵工自动化 , 2022 , 41 ( 12 ): 114 - 121 .
YUAN S , LIU H Q , QI M , et al . Research status of mechanical properties for composite propellant and its improvement technology [J ] . Ordnance Industry Automation , 2022 , 41 ( 12 ): 114 - 121 . (in Chinese)
MERMET-GUYENNET M R B , GIANFELICE DE CASTRO J , VAROL H S , et al . Size-dependent reinforcement of composite rubbers [J ] . Polymer , 2015 , 73 : 170 - 173 .
0
浏览量
734
下载量
0
CNKI被引量
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024360号