TiB<sub>2</sub>/B<sub>4</sub>C复相陶瓷自蔓延热爆炸烧结与性能表征

李云飞; 高鑫; 陈鹏万; 刘开源

doi:10.12382/bgxb.2023.0078

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TiB₂/B₄C复相陶瓷自蔓延热爆炸烧结与性能表征

更新时间：2025-08-18

- TiB₂/B₄C复相陶瓷自蔓延热爆炸烧结与性能表征
- SHS-assisted Shock Sintering and Characterization of TiB₂/B₄C Composite Ceramics
- 兵工学报 2024年45卷第1期页码：26-34
- 作者机构：
  
  1. 北京理工大学爆炸科学与技术国家重点实验室, 北京 100081
  2. 北京理工大学前沿技术研究院, 山东济南 250307
- 作者简介：
  
  * 邮箱: gaoxin@bit.edu.cn
- 基金信息：
  
  北京理工大学青年教师学术启动计划项目(SQD-202002004);国家自然科学基金项目(12072037)
- DOI：10.12382/bgxb.2023.0078
  中图分类号：
- 收稿：2023-02-13，
  
  网络出版：2024-02-06，
  
  纸质出版：2024-01-30
- 稿件说明：
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李云飞, 高鑫, 陈鹏万, 等. TiB₂/B₄C复相陶瓷自蔓延热爆炸烧结与性能表征[J]. 兵工学报, 2024,45(1):26-34.

Yunfei LI, Xin GAO, Pengwan CHEN, et al. SHS-assisted Shock Sintering and Characterization of TiB₂/B₄C Composite Ceramics[J]. Acta Armamentarii, 2024, 45(1): 26-34.
李云飞, 高鑫, 陈鹏万, 等. TiB₂/B₄C复相陶瓷自蔓延热爆炸烧结与性能表征[J]. 兵工学报, 2024,45(1):26-34. DOI： 10.12382/bgxb.2023.0078.

Yunfei LI, Xin GAO, Pengwan CHEN, et al. SHS-assisted Shock Sintering and Characterization of TiB₂/B₄C Composite Ceramics[J]. Acta Armamentarii, 2024, 45(1): 26-34. DOI： 10.12382/bgxb.2023.0078.

摘要

为了探究高硬度复相陶瓷高效且低成本的制备方法

利用自蔓延高温合成结合爆炸烧结技术

开展制备二硼化钛/碳化硼(TiB

复相陶瓷的研究

成功制备厚度约为1cm、直径约为5cm的TiB

C复相陶瓷块体。烧结样品物相和微观结构分析表征结果表明:烧结样品中TiB

相和B

C相分布均匀

截面观察到致密的微米级颗粒。该方法制备的样品致密度和硬度较高

随冲击压力不同

致密度范围在90%~93%之间

相应平均维氏硬度为16.64~17.35GPa;根据不同条件下回收样品的微结构、致密度等分析

冲击压力和起爆时刻生坯温度对TiB

C复相陶瓷烧结质量有重要影响;冲击压力为40GPa

生坯温度为1800K时

烧结致密度为93%;为进一步提高烧结质量

应提高冲击压力或冲击波作用时间。研究表明自蔓延热爆炸烧结技术是一种高效且低成本的高硬度复相陶瓷的制备方法。

Abstract

In order to explore the efficient and low-cost preparation method of high hardness composite ceramics

the titanium diboride/boron carbide (TiB

C) composite ceramics with a thickness of about 1 cm and a diameter of about 5cm was fabricated by SHS-assisted shock sintering method. The results of phase and microstructure analysis show that TiB

phase and B

C phase are evenly distributed in the sintered samples

and dense micron particles are observed in the cross section. The density and hardness of the samples prepared by this method are relatively high. The density ranges from 90% to 93% with the change of shock pressure

and the corresponding average Vickers hardness ranges from 16.64GPa to 17.35GPa. The analysis of the microstructures and densities of the recovered samples under different conditions show that the shock pressure and the pre-detonation temperature have an important effect on the consolidated quality of TiB

C composite ceramics. When the shock pressure is 40GPa and the temperature is 1500℃

the density of sintered sample is 93%. The shock pressure or shock time should be increased to improve the sintering quality. The results show that SHS-assisted shock sintering method is an efficient and low-cost preparation method for high hardness composite ceramics.

关键词

Keywords

references

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DOI：10.12382/bgxb.2023.0078

摘要

Abstract

关键词

Keywords

references

TiB₂/B₄C复相陶瓷自蔓延热爆炸烧结与性能表征

SHS-assisted Shock Sintering and Characterization of TiB₂/B₄C Composite Ceramics