弹道冲击下石墨烯和聚乙烯改性芳纶织物的钝伤防护性能

王哲; 刘鹏; 陈婧; 黄广炎; 张宏

doi:10.12382/bgxb.2022.0578

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弹道冲击下石墨烯和聚乙烯改性芳纶织物的钝伤防护性能

更新时间：2025-08-18

- 弹道冲击下石墨烯和聚乙烯改性芳纶织物的钝伤防护性能
- Blunt Trauma Resistance of Graphene and Polyethylene-modified Aramid Fabrics under Ballistic Impact
- 兵工学报 2024年45卷第1期页码：35-43
- 作者机构：
  
  1. 北京理工大学爆炸科学与技术国家重点实验室, 北京 100081
  2. 北京理工大学重庆创新中心现代兵器技术实验室, 重庆 401120
- 作者简介：
  
  * 邮箱: hong.zhang@bit.edu.cn
- 基金信息：
  
  国家自然科学基金青年项目(12002051);爆炸科学与技术国家重点实验室项目(QNKT21-4);重庆市科学技术局项目(CSTC2021jcyj-msxmX0666)
- DOI：10.12382/bgxb.2022.0578
  中图分类号：
- 收稿：2022-06-28，
  
  网络出版：2024-02-06，
  
  纸质出版：2024-01-30
- 稿件说明：
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王哲, 刘鹏, 陈婧, 等. 弹道冲击下石墨烯和聚乙烯改性芳纶织物的钝伤防护性能[J]. 兵工学报, 2024,45(1):35-43.

Zhe WANG, Peng LIU, Jing CHEN, et al. Blunt Trauma Resistance of Graphene and Polyethylene-modified Aramid Fabrics under Ballistic Impact[J]. Acta Armamentarii, 2024, 45(1): 35-43.
王哲, 刘鹏, 陈婧, 等. 弹道冲击下石墨烯和聚乙烯改性芳纶织物的钝伤防护性能[J]. 兵工学报, 2024,45(1):35-43. DOI： 10.12382/bgxb.2022.0578.

Zhe WANG, Peng LIU, Jing CHEN, et al. Blunt Trauma Resistance of Graphene and Polyethylene-modified Aramid Fabrics under Ballistic Impact[J]. Acta Armamentarii, 2024, 45(1): 35-43. DOI： 10.12382/bgxb.2022.0578.

摘要

芳纶凭借其轻质高强的特点广泛应用于防弹领域。为提高单层芳纶织物的抗钝伤能力

采用热塑性树脂聚乙烯(Polythene

PE)与石墨烯纳米粒子表面改性方法提升芳纶织物的抗钝伤性能。以背衬凹陷为标准

对不同质量配比改性芳纶织物的抗钝伤能力和能量吸收特性进行测试对比。对比结果表明:石墨烯和PE两种改性方法均可提升芳纶织物的抗钝伤能力

其中PE改性方法使得改性织物面密度增加较小但抗钝伤能力显著提升

10%PE的防弹能力和比吸能值较纯芳纶分别提升了18.0%和30.8%;石墨烯改性织物刚性的增加使其低速抗钝伤能力增强

但是过大的纱线间摩擦使其高速防护能力减弱

2%石墨烯粉体为石墨烯改性织物的最佳配比。此外

优化验证得到了2层10%PE和13层的6层正交超高分子量PE无纬布防弹衣组合设计。

Abstract

Aramid is widely used in the field of ballistic protection due to its light weight and high strength. In order to improve the trauma resistance of single-layer aramid fabrics

the surface modification methods of thermoplastic resin polyethylene (PE) and graphene nanoparticles (GR) are used innovatively to improve the ballistic performance of aramid fabrics. The trauma resistance and energy absorption of modified aramid fabrics with different mass ratios are studied based on the backface significance (BFS). The results show that both graphene and polyethylene modification methods can improve the blunt trauma resistance. The surface density of the modified fabric is increased slightly by polyethylene modification

but the resistance to blunt injury is significantly improved. Compared with pure aramid fabric

the bullet-proof ability and specific energy absorption value of 10% PE are increased by 18.0% and 30.8%

respectively. The increased rigidity of graphene-modified fabric increases its resistance to blunt injury at low speed

but the excessive inter-yarn friction weakens its resistance to blunt injury at high speed. 2% GR is the best ratio for graphene-modified fabric. In addition

the combined design of body armor with 2 layers of 10% PE and 13 layers of six layers of orthogonal UHMWPE unidrectional fabric is obtained through optimization and verification.

关键词

Keywords

references

中华人民共和国公安部 . 警用防弹衣:GA 141—2010 [S ] . 北京 : 中国标准出版社 , 2010 .

Ministry of Public Security of the People’s Republic of China . Police bulletproof vest:GA 141—2010 [S ] . Beijing : China Standard Press , 2010 . (in Chinese)

袁承军 . 软质防弹材料现状及防弹衣发展趋势 [J ] . 轻兵器 , 2005 ( 10 ): 8 - 9 .

YUAN C J . Current status of soft bulletproof materials and the development trend of bulletproof vests [J ] . Small Arms , 2005 ( 10 ): 8 - 9 . (in Chinese)

CHEN X , CHAUDHRY I . Ballistic protection [J ] . Textiles for Protection , 2005 : 529 - 556 .

QIN J B , GUO B R , ZHANG L , et al . Soft armor materials constructed with Kevlar fabric and a novel shear thickening fluid [J ] . Composites Part B.Engineering , 2020 , 183 ( 2 ): 107681 - 107686 .

石凌飞 , 刘春美 . “警盾-2019”防护装备公开比测活动概况及启示 [J ] . 警察技术 , 2020 ( 1 ): 62 - 68 .

SHI L F , LIU C M . Overview and insights of the “Police Shield-2019” protective equipment open comparison test activity [J ] . Police Technology , 2020 ( 1 ): 62 - 68 . (in Chinese)

何业茂 , 焦亚男 , 周庆 , 等 . 弹道防护用先进复合材料弹道响应的研究进展 [J ] . 复合材料学报 , 2021 , 38 ( 5 ): 1331 - 1347 .

HE Y M , JIAO Y N , ZHOU Q , et al . Advances in ballistic response of advanced composite materials for ballistic protection [J ] . Acta Materiae Compositae Sinica , 2021 , 38 ( 5 ): 1331 - 1347 . (in Chinese)

YANG Y F , CHEN X G . Study of energy absorption and failure modes of constituent layers in body armour panels [J ] . Composites Part B:Engineering , 2016 , 98 ( 1 ): 250 - 259 . DOI: 10.1016/j.compositesb.2016.04.071 http://doi.org/10.1016/j.compositesb.2016.04.071 https://linkinghub.elsevier.com/retrieve/pii/S1359836816305236 https://linkinghub.elsevier.com/retrieve/pii/S1359836816305236

ABTEW M A , BOUSSU F , BRUNIAUX P , et al . Ballistic impact mechanisms-a review on textiles and fibre-reinforced composites impact responses [J ] . Composite Structures , 2019 , 223 : 110966 . DOI: 10.1016/j.compstruct.2019.110966 http://doi.org/10.1016/j.compstruct.2019.110966 https://linkinghub.elsevier.com/retrieve/pii/S0263822318343411 https://linkinghub.elsevier.com/retrieve/pii/S0263822318343411

王凤德 , 陈超峰 , 朱建生 , 等 . 对位芳纶在防弹领域的应用 [J ] . 高科技纤维与应用 , 2011 , 36 ( 3 ): 8 - 12 .

WANG F D , CHEN C F , ZHU J S , et al . Application of para-aramid in ballistic protection [J ] . Hi-Tech Fiber & Application , 2011 , 36 ( 3 ): 8 - 12 . (in Chinese)

乔咏梅 , 余铜辉 . 软质防弹衣结构分析与性能研究 [J ] . 警察技术 , 2017 ( 3 ): 81 - 84 .

QIAO Y M , YU T H . Structure analysis and performance research of soft body armor [J ] . Police Technology , 2017 ( 3 ): 81 - 84 . (in Chinese)

李晓霞 , 赖西南 , 王建民 , 等 . 高速小口径步枪弹致防弹衣后猪背部钝性损伤特点 [J ] . 第三军医大学学报 , 2012 , 34 ( 18 ): 1811 - 1813 .

LI X X , LAI X N , WANG J M , et al . Features of blunt wound in back of pig wearing composite armour hit by high speed microstomia Rifle bullet [J ] . Acta Academiae Medicinae Militaris Tertiae , 2012 , 34 ( 18 ): 811 - 1813 . (in Chinese)

张波 , 赖西南 , 康建毅 , 等 . 步枪弹击中背部防弹衣后脊柱脊髓钝性损伤的生物力学机制 [J ] . 中华创伤杂志 , 2015 , 31 ( 3 ): 278 - 281 .

ZHANG B , LAI X N , KANG J Y , et al . Biomechanical mechanism of blunt spinal cord trauma after rifle bullets hitting back of body armor [J ] . Chinese Journal of Trauma , 2015 , 31 ( 3 ): 278 - 281 . (in Chinese)

周庆 , 刘婷 , 何业茂 . 防弹装甲中新型抗凹陷材料的研究 [J ] . 中国个体防护装备 , 2019 ( 1 ): 22 - 26 .

ZHOU Q , LIU T , HE Y M . Study on new anti-trauma material in bulletproof armour [J ] . China Personal Protection Equipment , 2019 ( 1 ): 22 - 26 . (in Chinese)

王天坤 , 俞科静 , 钱坤 , 等 . STF/UHMWPE复合材料的高速冲击性能 [J ] . 材料科学与工程学报 , 2015 , 33 ( 6 ): 895 - 898 .

WANG T K , YU K J , QIAN K , et al . High speed impact properties of STF/UHMWPE composites [J ] . Journal of Materials Science and Engineering , 2015 , 33 ( 6 ): 895 - 898 . (in Chinese)

CAO M J , CHEN L , XU R Z , et al . Effect of the temperature on ballistic performance of UHMWPE laminate with limited thickness [J ] . Composite Structures , 2021 , 277 : 114638 . DOI: 10.1016/j.compstruct.2021.114638 http://doi.org/10.1016/j.compstruct.2021.114638 https://linkinghub.elsevier.com/retrieve/pii/S0263822321010989 https://linkinghub.elsevier.com/retrieve/pii/S0263822321010989

饶崛 , 徐卫林 . 热状态下UHMWPE纤维的力学性能 [J ] . 纺织学报 , 2009 , 30 ( 1 ): 5 - 8 ,17.

RAO J , XU W L . Mechanical properties of UHMWPE fiber under heating state [J ] . Journal of Textile Research , 2009 , 30 ( 1 ): 5 - 8 ,17. (in Chinese)

SAPOZHNIKOV S B , KUDRYAVTSEV O A , ZHIKHAREV M V . Fragment ballistic performance of homogenous and hybrid thermoplastic composites [J ] . International Journal of Impact Engineering , 2015 , 81 : 8 - 16 . DOI: 10.1016/j.ijimpeng.2015.03.004 http://doi.org/10.1016/j.ijimpeng.2015.03.004 https://linkinghub.elsevier.com/retrieve/pii/S0734743X15000378 https://linkinghub.elsevier.com/retrieve/pii/S0734743X15000378

BANDARU A K , CHAVAN V V , AHMAD S , et al . Ballistic impact response of Kevlar® reinforced thermoplastic composite armors [J ] . International Journal of Impact Engineering , 2016 , 89 : 1 - 13 . DOI: 10.1016/j.ijimpeng.2015.10.014 http://doi.org/10.1016/j.ijimpeng.2015.10.014 https://linkinghub.elsevier.com/retrieve/pii/S0734743X15002201 https://linkinghub.elsevier.com/retrieve/pii/S0734743X15002201

IGNATOVA A V , KUDRYAVTSEV O A , ZHIKHAREV M V . Influence of surface polymer coating on ballistic impact response of multi-layered fabric composites:experimental and numerical study [J ] . International Journal of Impact Engineering , 2020 , 144 : 103654 . DOI: 10.1016/j.ijimpeng.2020.103654 http://doi.org/10.1016/j.ijimpeng.2020.103654 https://linkinghub.elsevier.com/retrieve/pii/S0734743X2030155X https://linkinghub.elsevier.com/retrieve/pii/S0734743X2030155X

陈虹 , 艾青松 , 吴中伟 , 等 . 石墨烯改性防弹材料研究进展 [J ] . 工程塑料应用 , 2021 , 49 ( 2 ): 162 - 166 .

CHEN H , AI Q S , WU Z W , et al . Research progress of graphene-modified bulletproof materials [J ] . Engineering Plastics Application , 2021 , 49 ( 2 ): 162 - 166 . (in Chinese)

TAN Z H , LI W H , HUANG W W . The effect of graphene on the yarn pull-out force and ballistic performance of Kevlar fabrics impregnated with shear thickening fluids [J ] . Smart Materials and Structures , 2018 , 27 ( 7 ): 75048 . DOI: 10.1088/1361-665X/aaca4b http://doi.org/10.1088/1361-665X/aaca4b https://iopscience.iop.org/article/10.1088/1361-665X/aaca4b https://iopscience.iop.org/article/10.1088/1361-665X/aaca4b

MANIGANDAN S , GUNASEKAR P , NITHYA S , et al . Experimental analysis of graphene nanocomposite on Kevlar [J ] . IOP Conference Series: Materials Science and Engineering , 2017 , 225 ( 1 ): 012061 . DOI: 10.1088/1757-899X/225/1/012061 http://doi.org/10.1088/1757-899X/225/1/012061 https://iopscience.iop.org/article/10.1088/1757-899X/225/1/012061 https://iopscience.iop.org/article/10.1088/1757-899X/225/1/012061

吴中伟 , 张慧 , 艾青松 , 等 . 芳纶防弹防刺材料研究 [J ] . 合成纤维 , 2021 , 50 ( 6 ): 36 - 40 .

WU Z W , ZHANG H , AI Q S , et al . Research on aramid ballistic and stab-proof materials [J ] . Synthetic Fiber in China , 2021 , 50 ( 6 ): 36 - 40 . (in Chinese)

GOWER H L , CRONIN D S , PLUMTREE A . Ballistic impact response of laminated composite panels [J ] . International Journal of Impact Engineering , 2008 , 35 ( 9 ): 1000 - 1008 . DOI: 10.1016/j.ijimpeng.2007.07.007 http://doi.org/10.1016/j.ijimpeng.2007.07.007 https://linkinghub.elsevier.com/retrieve/pii/S0734743X07001200 https://linkinghub.elsevier.com/retrieve/pii/S0734743X07001200

MAWKHLIENG U , MAJUMDAR A . Designing of hybrid soft body armour using high-performance unidirectional and woven fabrics impregnated with shear thickening fluid [J ] . Composite Structures , 2020 , 253 : 112776 . DOI: 10.1016/j.compstruct.2020.112776 http://doi.org/10.1016/j.compstruct.2020.112776 https://linkinghub.elsevier.com/retrieve/pii/S0263822320327021 https://linkinghub.elsevier.com/retrieve/pii/S0263822320327021

MA Y , LEI Z K , HUANG G Y , et al . Energy absorption analysis of STF/Kevlar composite fabric based on 3D morphology of impact basin under low-speed impact [J ] . Composite Structures , 2022 , 283 : 115152 . DOI: 10.1016/j.compstruct.2021.115152 http://doi.org/10.1016/j.compstruct.2021.115152 https://linkinghub.elsevier.com/retrieve/pii/S0263822321015671 https://linkinghub.elsevier.com/retrieve/pii/S0263822321015671

KARAHAN M , KUŞ A , EREN R . An investigation into ballistic performance and energy absorption capabilities of woven aramid fabrics [J ] . International Journal of Impact Engineering , 2008 , 35 : 499 - 510 . DOI: 10.1016/j.ijimpeng.2007.04.003 http://doi.org/10.1016/j.ijimpeng.2007.04.003 https://linkinghub.elsevier.com/retrieve/pii/S0734743X07000644 https://linkinghub.elsevier.com/retrieve/pii/S0734743X07000644

DUAN Y , KEEFE M , BOGETTI T A , et al . A numerical investigation of the influence of friction on energy absorption by a high-strength fabric subjected to ballistic impact [J ] . International Journal of Impact Engineering , 2006 , 32 : 1299 - 1312 . DOI: 10.1016/j.ijimpeng.2004.11.005 http://doi.org/10.1016/j.ijimpeng.2004.11.005 https://linkinghub.elsevier.com/retrieve/pii/S0734743X04002192 https://linkinghub.elsevier.com/retrieve/pii/S0734743X04002192

ZHOU Y , CHEN X G , WELLS G . Influence of yarn gripping on the ballistic performance of woven fabrics from ultra-high molecular weight polyethylene fibre [J ] . Composites Part B: Engineering , 2014 , 62 : 198 - 204 . DOI: 10.1016/j.compositesb.2014.02.022 http://doi.org/10.1016/j.compositesb.2014.02.022 https://linkinghub.elsevier.com/retrieve/pii/S1359836814000997 https://linkinghub.elsevier.com/retrieve/pii/S1359836814000997

NAVEEN J , JAWAID M , ZAINUDIN E S , et al . Effect of graphene nanoplatelets on the ballistic performance of hybrid Kevlar/Cocos nucifera sheath-reinforced epoxy composites [J ] . Textile Research Journal , 2019 , 89 ( 21/22 ): 4349 - 4362 . DOI: 10.1177/0040517519833970 http://doi.org/10.1177/0040517519833970 http://journals.sagepub.com/doi/10.1177/0040517519833970 http://journals.sagepub.com/doi/10.1177/0040517519833970 This study investigated the effect of graphene nanoplatelets (GnPs) on the ballistic performance of Kevlar/ Cocos nucifera sheath-reinforced epoxy composites. GnPs with different wt. % (0%, 0.25%, 0.50%) were integrated into epoxy resin through ultra-sonication. Laminated composites were fabricated by incorporating Kevlar and Cocos nucifera sheath layers into the epoxy/GnP mixture by the hand lay-up method followed by hot pressing. Nine- and 12-layered laminates were fabricated with different numbers of Kevlar and Cocos nucifera sheath plies. Ballistic tests were conducted using a single-stage gas gun experimental setup with an 8 mm hemispherical stainless steel projectile. The results showed that the addition of GnPs improved the energy absorption by 8.5% (nine plies) and 12.88% (12 plies) and the ballistic limit by 4.28% (nine plies) and 6.17% (12 plies), respectively of Kevlar/epoxy/GnP composites at 0.25 wt. %. However, hybrid Kevlar/ Cocos nucifera sheath/epoxy/GnP composites and Cocos nucifera sheath/epoxy/GnP laminated composites decreased the energy absorption and ballistic limit after the addition of GnPs. This is because the addition of GnPs improved the interfacial interactions between the fiber and GnP modified epoxy matrix, which is inappropriate to absorb and dissipate the kinetic energy of the projectile. Statistical analysis was carried out using one-way analysis of variance and it was shown that there is a statistically significant difference between the obtained ballistic properties of the laminates.

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