1. 哈尔滨工程大学 航天与建筑工程学院,黑龙江 哈尔滨 150001
2. 哈尔滨工业大学 航天学院,黑龙江 哈尔滨 150001
[ "邹广平(1963—),男,教授,博士生导师,研究方向为冲击动力学、实验力学。E-mail:zouguangping@hrbeu.edu.cn;" ]
[ "吴松阳(1998—),男,硕士研究生,研究方向为冲击动力学、实验力学。E-mail:1823447620qq.com;" ]
[ "徐舒博(1995—),男,博士研究生,研究方向为材料学-碳/陶瓷材料。E-mail:417964333@qq.com;" ]
唱忠良(1982—),男,讲师,博士,研究方向为冲击动力学、实验力学。E-mail:lxsy@hrbeu.edu.cn
[ "王宣(1999—),女,硕士研究生,研究方向为冲击动力学、复合材料力学。E-mail:wangx180501@163.com" ]
收稿:2021-11-15,
纸质出版:2023-03-28
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邹广平, 吴松阳, 徐舒博, 等. 石墨烯/陶瓷颗粒增强聚氨酯基复合材料动态压缩性能[J]. 兵工学报, 2023,44(3):728-735.
Guangping ZOU, Songyang WU, Shubo XU, et al. Dynamic Compressive Properties of Graphene/Ceramic Particle Reinforced Polyurethane-Based Composites[J]. Acta Armamentarii, 2023, 44(3): 728-735.
邹广平, 吴松阳, 徐舒博, 等. 石墨烯/陶瓷颗粒增强聚氨酯基复合材料动态压缩性能[J]. 兵工学报, 2023,44(3):728-735. DOI: 10.12382/bgxb.2021.0777.
Guangping ZOU, Songyang WU, Shubo XU, et al. Dynamic Compressive Properties of Graphene/Ceramic Particle Reinforced Polyurethane-Based Composites[J]. Acta Armamentarii, 2023, 44(3): 728-735. DOI: 10.12382/bgxb.2021.0777.
聚氨酯良好的力学性能使其广泛应用于各种领域,通过在聚氨酯基体中引入石墨烯增强体,能够大幅度增强聚氨酯基复合材料的各项性能。为得到具有高抗冲击能力的聚氨酯基复合材料,使用原位聚合法制备氧化石墨烯增强聚氨酯,通过霍普金森杆装置对其进行不同应变率下的动态压缩试验。采用无压渗透法加入直径3.3 mm的Al
2
O
3
颗粒陶瓷作为新的增强相。对石墨烯/颗粒陶瓷增强聚氨酯基复合材料进行动态围压实验,得到试样的应力-应变曲线。应用LS-DYNA动力学仿真软件建立复合材料有限元仿真模型,结合实验数据验证仿真的可靠性。分析复合材料在动态围压下的变形过程和损伤机理,开展不同粒径试样在动态围压下的仿真分析,讨论不同粒径的颗粒陶瓷对复合材料动态压缩的力学性能影响。研究结果表明:颗粒陶瓷粒径与复合材料的抗压强度密切相关,随着陶瓷颗粒粒径减小,即陶瓷颗粒数量增多,间隙减小时,复合材料的抗压性能也相应提高。
The good mechanical properties of polyurethane make it widely used in various fields. By introducing graphene reinforcement into the polyurethane matrix
it can greatly enhance the properties of the polyurethane-based composites. To obtain the polyurethane-based composites with high impact resistance
graphene oxide reinforced polyurethane was prepared by in-situ polymerization
and dynamic compression tests at different strain rates were carried out with the Hopkinson bar device. On this basis
3.3 mm diameter Al
2
O
3
granular ceramics was added as a new reinforcing phase by the pressureless infiltration method. The dynamic confining pressure experiment of graphene / granular ceramic reinforced polyurethane-based composites is p
erformed
and the stress-strain curve of the sample is obtained. The finite element simulation model of the composite is established by using LS-DYNA. Combined with the experimental data
the reliability of the simulation is verified
the deformation process and damage mechanism of the composite under dynamic confining pressure are analyzed
the simulation analysis of the samples with different particle sizes under dynamic confining pressure is carried out
and the influence of ceramic particles with different particle sizes on the dynamic compression mechanical properties of the composite is discussed. The results show that: the particle size of ceramic particles is closely related to the compressive strength of the composites; with the decrease of ceramic particle size
i.e.
the number of ceramic particles increases and the particle gap decreases
the compressive properties of the composite are improved.
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HU F , GAO J , ZHANG B , et al. Effects of modified Al 2 O 3 -decorated ionic liquid on the mechanical properties and impact resistance of a polyurethane elastomer [J ] . Materials , 2021 , 14 ( 16 ): 4712 . DOI: 10.3390/ma14164712 http://doi.org/10.3390/ma14164712 https://www.mdpi.com/1996-1944/14/16/4712 https://www.mdpi.com/1996-1944/14/16/4712 In this work, a new composite material with excellent dynamic impact resistance and outstanding quasi-static mechanical properties was synthesized. The composite material is composed of a polyurethane elastomer and a novel nano-polymer. The nano-polymer was composed of silane coupling agent-modified alumina microspheres and functionalized ionic liquids by double bond polymerization. The universal testing machine and split Hopkinson pressure bar were used to characterize the compression behavior, strength and energy absorption of the composite materials under static and dynamic conditions. Additionally, the comprehensive mechanical properties of polyurethane elastomer with different nano-polymer loadings (0.5–2.5 wt.%) were studied. The results show that whether it was static compression or dynamic impact, the polyurethane elastomer with 1% nano-polymer had the best performance. For the composite material with the best properties, its compressive yield strength under the static compression was about 61.13% higher than that of the pure polyurethane elastomer, and its energy absorption of dynamic impacts was also increased by about 15.53%. Moreover, the shape memory effect was very good (shape recovery is approximately 95%), and the microscopic damage degree was relatively small. This shows that the composite material with the best properties can withstand high compression loads and high-speed impacts. The developed composite material is a promising one for materials science and engineering, especially for protection against compression and impacts.
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