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SHS-assisted Shock Sintering and Characterization of TiB2/B4C Composite Ceramics
- Acta Armamentarii Vol. 45, Issue 1, Pages: 26-34(2024)
- 作者机构：
1. 北京理工大学 爆炸科学与技术国家重点实验室, 北京 100081
2. 北京理工大学 前沿技术研究院, 山东 济南 250307
- 作者简介：
- 基金信息：
DOI：10.12382/bgxb.2023.0078
CLC：Received：13 February 2023，
Published Online：06 February 2024，
Published：30 January 2024
- 稿件说明：
移动端阅览
Yunfei LI, Xin GAO, Pengwan CHEN, et al. SHS-assisted Shock Sintering and Characterization of TiB2/B4C Composite Ceramics[J]. Acta Armamentarii, 2024, 45(1): 26-34.
Yunfei LI, Xin GAO, Pengwan CHEN, et al. SHS-assisted Shock Sintering and Characterization of TiB2/B4C Composite Ceramics[J]. Acta Armamentarii, 2024, 45(1): 26-34. DOI： 10.12382/bgxb.2023.0078.
摘要
为了探究高硬度复相陶瓷高效且低成本的制备方法
利用自蔓延高温合成结合爆炸烧结技术
开展制备二硼化钛/碳化硼(TiB
2
/B
4
C)
复相陶瓷的研究
成功制备厚度约为1cm、直径约为5cm的TiB
2
/B
4
C复相陶瓷块体。烧结样品物相和微观结构分析表征结果表明:烧结样品中TiB
2
相和B
4
C相分布均匀
截面观察到致密的微米级颗粒。该方法制备的样品致密度和硬度较高
随冲击压力不同
致密度范围在90%~93%之间
相应平均维氏硬度为16.64~17.35GPa;根据不同条件下回收样品的微结构、致密度等分析
冲击压力和起爆时刻生坯温度对TiB
2
/B
4
C复相陶瓷烧结质量有重要影响;冲击压力为40GPa
生坯温度为1800K时
烧结致密度为93%;为进一步提高烧结质量
应提高冲击压力或冲击波作用时间。研究表明自蔓延热爆炸烧结技术是一种高效且低成本的高硬度复相陶瓷的制备方法。
Abstract
In order to explore the efficient and low-cost preparation method of high hardness composite ceramics
the titanium diboride/boron carbide (TiB
2
/B
4
C) composite ceramics with a thickness of about 1 cm and a diameter of about 5cm was fabricated by SHS-assisted shock sintering method. The results of phase and microstructure analysis show that TiB
2
phase and B
4
C phase are evenly distributed in the sintered samples
and dense micron particles are observed in the cross section. The density and hardness of the samples prepared by this method are relatively high. The density ranges from 90% to 93% with the change of shock pressure
and the corresponding average Vickers hardness ranges from 16.64GPa to 17.35GPa. The analysis of the microstructures and densities of the recovered samples under different conditions show that the shock pressure and the pre-detonation temperature have an important effect on the consolidated quality of TiB
2
/B
4
C composite ceramics. When the shock pressure is 40GPa and the temperature is 1500℃
the density of sintered sample is 93%. The shock pressure or shock time should be increased to improve the sintering quality. The results show that SHS-assisted shock sintering method is an efficient and low-cost preparation method for high hardness composite ceramics.
关键词
Keywords
references
郭景坤 . 中国先进陶瓷研究及其展望 [J ] . 材料研究学报 , 1997 ( 6 ): 594 - 600 . 本文综述了中国在先进陶瓷,包括结构陶瓷和功能陶瓷的研究概况及其展望。从本世纪五十年代以来,我国即开展先进陶瓷的基础研究和应用研究,在此基础上,逐步形成了在这一领域中的研究趋向,即多相复合陶瓷、纳米陶瓷和陶瓷材料的剪裁与设计。
GUO J K . The research on advanced ceramics and its prospects in China [J ] . Chinese Journal of Materials Research , 1997 ( 6 ): 594 - 600 . (in Chinese) In this paper, the progress and its prospect on advanced ceramics, containing structural ceramics and functional ceramics, was reviewed. Since 50's of this century, the studies of advanced ceramics was carrying on in China. The research work was emphasize
姚亿文 , 杨飞跃 , 赵爽 , 等 . 新型陶瓷涂层的制备、结构调控及应用研究进展 [J ] . 材料导报 , 2022 , 36 ( 23 ): 66 - 72 .
YAO Y W , YANG F Y , ZHAO S , et al . Research progress on preparation, structure control and applications of novel ceramic coatings [J ] . Materials Reports , 2022 , 36 ( 23 ): 66 - 72 . (in Chinese)
RUBINK W S , AGEH V , LIDE H , et al . Spark plasma sintering of B 4 C and B 4 C-TiB 2 composites: deformation and failure mechanisms under quasistatic and dynamic loading [J ] . Journal of the European Ceramic Society , 2021 ( 1 ): 3321 - 3332 .
TOROSYAN K S , SEDEGOV A S , KUSKOV K V , et al . Reactive, nonreactive, and flash spark plasma sintering of Al 2 O 3 /SiC composites-a comparative study [J ] . Journal of the American Ceramic Society , 2020 , 103 ( 1 ): 520 - 530 . DOI: 10.1111/jace.v103.1 http://doi.org/10.1111/jace.v103.1 https://ceramics.onlinelibrary.wiley.com/toc/15512916/103/1 https://ceramics.onlinelibrary.wiley.com/toc/15512916/103/1
YANG H L , LI Q G , WANG Z , et al . Effect of graphene on microstructure and mechanical properties of Si 3 N 4 /SiC ceramics [J ] . ES Materials & Manufacturing , 2021 , 12 : 29 - 34 .
HU T Y , YAO M Y , HU D L , et al . Effect of mechanical alloying on sinterability and phase evolution in pressure-less sintered TiB 2 -TiC ceramics [J ] . Journal of Materiomics , 2019 , 5 ( 4 ): 670 - 678 . DOI: 10.1016/j.jmat.2019.05.001 http://doi.org/10.1016/j.jmat.2019.05.001 https://linkinghub.elsevier.com/retrieve/pii/S2352847819300310 https://linkinghub.elsevier.com/retrieve/pii/S2352847819300310
陈代梦 . TiB 2 基复相陶瓷的烧结及其力学性能研究 [D ] . 绵阳 : 西南科技大学 , 2022 .
CHEN D M . Study on sintering and mechanical properties of TiB 2 -based composite ceramics [D ] . Mianyang : Southwest University of Science and Technology , 2022 . (in Chinese)
王晓楠 , 陶强 , 左斌 , 等 . B 4 C-TiB 2 复相陶瓷材料研究进展 [J ] . 陶瓷学报 , 2020 , 41 ( 6 ): 783 - 795 .
WANG X N , TAO Q , ZUO B , et al . Research progress of B 4 C-TiB 2 composite ceramics [J ] . Journal of Ceramics , 2020 , 41 ( 6 ): 783 - 795 . (in Chinese)
CHEN D M , ZHANG K B , ZENG J J , et al . Microstructure and mechanical properties of TiB 2 -B 4 C ceramics fabricated by hot-pressing [J ] . Ceramics International , 2021 , 47 ( 18 ): 25895 - 25900 . DOI: 10.1016/j.ceramint.2021.05.320 http://doi.org/10.1016/j.ceramint.2021.05.320 https://linkinghub.elsevier.com/retrieve/pii/S0272884221017223 https://linkinghub.elsevier.com/retrieve/pii/S0272884221017223
BAHARVANDI H R , HADIAN A M . Pressureless sintering of TiB 2 -B 4 C ceramic matrix composite [J ] . Journal of Materials Engineering and Performance , 2008 , 17 ( 6 ): 838 - 841 . DOI: 10.1007/s11665-007-9182-4 http://doi.org/10.1007/s11665-007-9182-4 http://link.springer.com/10.1007/s11665-007-9182-4 http://link.springer.com/10.1007/s11665-007-9182-4
ZHAO J , LI Q G , CAO W X , et al . Influences of B 4 C content and particle size on the mechanical properties of hot pressed TiB 2 -B 4 C composites [J ] . Journal of Asian Ceramic Societies , 2021 , 9 ( 3 ): 1239 - 1247 . DOI: 10.1080/21870764.2021.1953759 http://doi.org/10.1080/21870764.2021.1953759 https://www.tandfonline.com/doi/full/10.1080/21870764.2021.1953759 https://www.tandfonline.com/doi/full/10.1080/21870764.2021.1953759
CHEN D M , ZHANG K B , ZENG J J , et al . High-strength TiB 2 -B 4 C composite ceramics sintered by spark plasma sintering [J ] . International Journal of Applied Ceramic Technology , 2022 , 19 ( 4 ): 1949 - 1955 . DOI: 10.1111/ijac.v19.4 http://doi.org/10.1111/ijac.v19.4 https://ceramics.onlinelibrary.wiley.com/toc/17447402/19/4 https://ceramics.onlinelibrary.wiley.com/toc/17447402/19/4
张国军 . 反应合成非氧化物陶瓷材料 [J ] . 现代技术陶瓷 , 2022 , 43 ( 增刊1 ): 310 - 324 .
ZHANG G J . Reactive synthesis of non-oxide ceramics [J ] . Advanced Ceramics , 2022 , 43 ( S1 ): 310 - 324 . (in Chinese)
HU M H , BI N , LIU M M , et al . Synthes is and performance of TiB 2 -B 4 C composites by high pressure of TiC-B mixture [J ] . International Journal of Applied Ceramic Technology , 2020 , 17 ( 4 ): 1629 - 1635 . DOI: 10.1111/ijac.v17.4 http://doi.org/10.1111/ijac.v17.4 https://ceramics.onlinelibrary.wiley.com/toc/17447402/17/4 https://ceramics.onlinelibrary.wiley.com/toc/17447402/17/4
WANG B F , XIE F Y , LI Z C , et al . Explosive compaction of Al 2 O 3 nanopowders [J ] . Ceramics International , 2016 , 42 ( 7 ): 8460 - 8466 . DOI: 10.1016/j.ceramint.2016.02.066 http://doi.org/10.1016/j.ceramint.2016.02.066 https://linkinghub.elsevier.com/retrieve/pii/S0272884216300116 https://linkinghub.elsevier.com/retrieve/pii/S0272884216300116
LI J B , MING L , AI Y B , et al . Synthesis of bulk amorphous alloy from Fe-base powders by explosive consolidation [J ] . Metals Open Access Metallurgy Journal , 2018 , 8 ( 9 ): 727 .
ZHOU Q , CHEN P W . Fabrication and characterization of pure tungsten using the hot-shock consolidation [J ] . International Journal of Refractory Metals and Hard Materials , 2014 , 42 : 215 - 220 . DOI: 10.1016/j.ijrmhm.2013.09.008 http://doi.org/10.1016/j.ijrmhm.2013.09.008 https://linkinghub.elsevier.com/retrieve/pii/S0263436813001972 https://linkinghub.elsevier.com/retrieve/pii/S0263436813001972
张越举 . 爆炸压实烧结纳米陶瓷粉末研究 [D ] . 大连 : 大连理工大学 , 2007 .
ZHANG Y J . The research of explosive consolidation and sintering of nanometer ceramic powders [D ] . Dalian : Dalian University of Technology , 2007 . (in Chinese)
ZHOU Q , CHEN P W . Characterization of fine-grained W-10 wt.% Cu composite fabricated by hot-shock consolidation [J ] . International Journal of Refractory Metals and Hard Materials , 2015 , 52 : 137 - 142 . DOI: 10.1016/j.ijrmhm.2015.06.002 http://doi.org/10.1016/j.ijrmhm.2015.06.002 https://linkinghub.elsevier.com/retrieve/pii/S0263436815300573 https://linkinghub.elsevier.com/retrieve/pii/S0263436815300573
MASHIMO T , HUANG X S , TASHIRO S . Non-equilibrium W-Cu system alloy powder and bulk body prepared by mechanical alloying and shock compression [J ] . Journal of Materials Science Letters , 1997 , 16 ( 12 ): 1051 - 1054 . DOI: 10.1023/A:1018578725262 http://doi.org/10.1023/A:1018578725262 http://link.springer.com/10.1023/A:1018578725262 http://link.springer.com/10.1023/A:1018578725262
刘江昊 . SHS/QP法制备MgO纳米晶陶瓷及烧结致密化机理研究 [D ] . 武汉 : 武汉理工大学 , 2010 .
LIU J H . Manufacturing fully-dense MgO nanocrystalline ceramics by SHS/QP and investigating on the desification mechanism [D ] . Wuhan : Wuhan University of Technology , 2010 . (in Chinese)
MISHRA S K , DAS S K , SHERBACOV V . Fabrication of Al 2 O 3 -ZrB 2 in situ composite by SHS dynamic compaction: a novel approach [J ] . Composites Science and Technology , 2007 , 67 ( 11/12 ): 2447 - 2453 . DOI: 10.1016/j.compscitech.2006.12.017 http://doi.org/10.1016/j.compscitech.2006.12.017 https://linkinghub.elsevier.com/retrieve/pii/S026635380700022X https://linkinghub.elsevier.com/retrieve/pii/S026635380700022X
MISHRA S K , GOKUUL V , PASWAN S . Alumina-titanium diboride in situ composite by self-propagating high-temperature synthesis (SHS) dynamic compaction: effect of compaction pressure during synthesis [J ] . International Journal of Refractory Metals and Hard Materials , 2014 , 43 : 19 - 24 . DOI: 10.1016/j.ijrmhm.2013.10.018 http://doi.org/10.1016/j.ijrmhm.2013.10.018 https://linkinghub.elsevier.com/retrieve/pii/S0263436813002205 https://linkinghub.elsevier.com/retrieve/pii/S0263436813002205
程勇 , 苏勋家 , 侯根良 , 等 . 动态加压下自蔓延高温合成致密ZrC陶瓷 [J ] . 稀有金属材料与工程 , 2016 , 45 ( 8 ): 2155 - 2160 .
CHENG Y , SU X J , HOU G L , et al . Dense ZrC ceramics fabricated by self-propagating high temperature synthesis under dynamic pressing [J ] . Rare Metal Materials and Engineering , 2016 , 45 ( 8 ): 2155 - 2160 . (in Chinese)
胡铁铮 . 基于SHS技术的half-Heusler合金和Cu 2 Se化合物的超快速制备及热电性能研究 [D ] . 武汉 : 武汉理工大学 , 2019 .
HU T Z . Ultra-fast fabrication and thermoelectric performance of half-Heusler alloy and Cu 2 Se compound based on SHS technique [D ] . Wuhan : Wuhan University of Technology , 2019 . (in Chinese)
WANG L , WIXOM M R , THOMPSON L T . Structural and mechanical properties of TiB 2 and TiC prepared by self-propagating high-temperature synthesis/dynamic compaction [J ] . Journal of Materials Science , 1994 , 29 : 534 - 543 . DOI: 10.1007/BF01162518 http://doi.org/10.1007/BF01162518 http://link.springer.com/10.1007/BF01162518 http://link.springer.com/10.1007/BF01162518
TOMOSHIGE R , LI S , FUJITA M , et al . Hot dynamic densification of materials by utilizing underwater shock wave [C ] // Proceedings of Materials Science Forum . Switzerland : Trans Tech Publications Ltd. , 2012 , 706 : 793 - 798 .
SCHERBAKOV V A , GRYADUNOV A N , ALYMOV M I . Synthesis and characteristics of B 4 C-TiB 2 composite [J ] . Advanced Materials & Technologies , 2016 ( 4 ): 16 - 21 .
刘明明 , 胡美华 , 毕宁 , 等 . TiB 2 -B 4 C陶瓷复合材料高压烧结与性能表征 [J ] . 硅酸盐通报 , 2020 , 39 ( 3 ): 910 - 915 . 在5.0GPa及1500～2000℃的压力和温度条件下,采用高压烧结的方法制备了B4C含量分别为10％和30％的TiB2-B4C陶瓷复合材料.对TiB2-B4C陶瓷复合材料的物相、显微结构、密度、硬度、热导率、电阻率等进行了分析.结果表明:材料在高压下没有发现化学反应生成新的相;TiB2-B4C陶瓷复合材料具有较高的致密性,没有明显的气孔;TiB2-30％B4C在1800℃下硬度最高,在4.9N载荷下可达27.8GPa,在9.8N载荷下可达24.3GPa;在常温下,热导率可达30.42W/(m·K).
LIU M M , HU M H , BI N , et al . High-pressure sinte-ring and performance characterization of TiB 2 -B 4 C cera-mic composites [J ] . Bulletin of the Chinese Ceramic Society , 2020 , 39 ( 3 ): 910 - 915 . (in Chinese)
赵传荣 , 孔德仁 , 王胜强 , 等 . 飞片厚度对冲击波压力峰值衰减特性的影响分析 [J ] . 振动与冲击 , 2016 , 35 ( 3 ): 135 - 138 .
ZHAO C R , KONG D R , WANG S Q , et al . Influence of flyer’s thickness on the attenuation characteristics of shock wave’s pressure peak [J ] . Journal of Vibration and Shock , 2016 , 35 ( 3 ): 135 - 138 . (in Chinese)
钟云岭 , 郭香华 , 张庆明 . 冲击波在泡沫铝复合结构中的衰减特性理论分析 [J ] . 兵工学报 , 2014 , 35 ( 增刊2 ): 322 - 327 .
ZHONG Y L , GUO X H , ZHANG Q M . Study of the attenuation of shock wave in aluminum foam composite structures [J ] . Acta Armamentarii , 2014 , 35 ( S2 ): 322 - 327 . (in Chinese)
MARTA Z S . TiB 2 -based composites for ultra-high-temperature devices, fabricated by SHS, combining strong and weak exothermic reactions [J ] . Materials , 2013 , 6 ( 5 ): 1903 - 1919 . DOI: 10.3390/ma6051903 http://doi.org/10.3390/ma6051903 http://www.mdpi.com/1996-1944/6/5/1903 http://www.mdpi.com/1996-1944/6/5/1903
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