三硝基间苯二酚钡和三硝基间苯二酚铅复盐的晶体结构研究

兵工学报 ›› 1982, Vol. 3 ›› Issue (3): 31-37.

三硝基间苯二酚钡和三硝基间苯二酚铅复盐的晶体结构研究

堵祖岳

收稿日期:1981-02-28 修回日期:1981-02-28 上线日期:2014-12-25
通讯作者: 堵祖岳

The crystal Structure Research of Barium 2，4，6 - Trinitro-1，3—Dihyd- roxybenzene and Lead 2，4，6-Trinitro-l, 3-Dihydroxybenzene Complex

Du Zuyue

Received:1981-02-28 Revised:1981-02-28 Online:2014-12-25
Contact: Du Zuyue

摘要/Abstract

摘要：

本文对三硝基间苯二酚钡和三硝基间苯二酚铅复盐的晶体结构，用派特逊方法(Patterson)进行了测定。其晶体结构为单斜晶系，空间群P2／c，α=7.529、b = 8.077、c=8.681 Å、β=106°44′。对全部原予坐标参数和各向异性温度参数由887个衍射作全矩阵最小二乘修正、最终偏离因子R =0.106。结构测定表明它的结构属于类质同象，重原子(Pb，Ba)的周围有九个氧原子。

Abstract:

In this paper, The crystal structure of Barium 2，4，6-trinitro-l, 3-dihydro- xybenzene and Lead 2，4，6-trinitro-1，3-dihydroxy-benzene complex has been determined by patterson method. It is monoclinic, the space group being P2/c with ɑ=7.529，b =8.077，c = 8.681Å, β = 106°44′. The structure parameters (atomic coordinates and anisotropic temperature parameters) was refined by fu— 11-matrix least squares calculations to a final R=0.106 for 887 reflexion. The structural determination shows that its structure belongs to isomorphism and the heavy atoms (Ba. Pb) are surrounded by nine oxygen atoms.

堵祖岳. 三硝基间苯二酚钡和三硝基间苯二酚铅复盐的晶体结构研究[J]. 兵工学报, 1982, 3(3): 31-37.

Du Zuyue. The crystal Structure Research of Barium 2，4，6 - Trinitro-1，3—Dihyd- roxybenzene and Lead 2，4，6-Trinitro-l, 3-Dihydroxybenzene Complex[J]. Acta Armamentarii, 1982, 3(3): 31-37.