烷氧基苯基取代硫代双烯镍配合物近红外吸收材料的制备和表征

兵工学报 ›› 2009, Vol. 30 ›› Issue (9): 1227-1231.

烷氧基苯基取代硫代双烯镍配合物近红外吸收材料的制备和表征

周奋国，周涛，何兴权，刘大军，段潜

长春理工大学化学与环境工程学院，吉林长春130022

收稿日期:2008-03-01 上线日期:2014-12-25
通讯作者: 周奋国 E-mail:fenguozhou@163．com
作者简介:周奋国(1977-)，男，讲师，硕士。
基金资助:
长春理工大学基金资助项目( XJJ2006-07)

Preparation and Characterization of Near Infrared Absorbing Material Containing Dithiolene MetalComplexes Substituted by Alkoxyphenyl

ZHOU Fen-guo, ZHOU Tao, HE Xing-quan,LIU Da-jun, DUAN Qian

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, Jilin, China

Received:2008-03-01 Online:2014-12-25
Contact: ZHOU Fen-guo E-mail:fenguozhou@163．com

摘要/Abstract

摘要： 本文合成了乙氧基苯基、丁氧基苯基、十六烷氧基苯基取代3种硫代双烯镍配合物，并用红外光谱表征其结构。紫外一可见一近红外光谱测试表明这3种化合物近红外区的最大吸收波长分别为927，929和932 nm且具有较大的摩尔消光系数。在此基础上，将3种配合物用注射成型方法掺入PMMA树脂中制备了近红外吸收复合材料，3种材料在900～1000 nm范围内光密度大于3.7，在可见光区平均透过率大于30%，是很好的近红外吸收材料。

关键词: 有机高分子材料 , 近红外吸收材料 , 硫代双烯镍配合物 , 注射成型

Abstract: Three kinds of dithiolene metal complexes substituted by ethoxyphenyl, butoxyphenyl, hex- adecyloxyphenyl were synthesized and their structures were characterized by means of Infrared Spec?trum and ultraviolet-visible-near-infrared spectrum. Ultraviolet-visible-near-infrared spectrum testings of three compounds show that maximum absorption wavelengths in near infrared range are 927，929 and 932 nm with higher extinction coefficient respectively. Three kinds of near infrared absorbing PM- MA material containing the above-mentioned dithiolene metal complexes were prepared, of which opti?cal densities in the range of 900 ?I 000 nm are higher than 3.7 and the average transmittances in visi?ble range are higher 30 % . They are good near infrared absorbing materials.

Key words: organic polymer material , near infrared absorbing material , dithiolene metal complexes , injection moulding

中图分类号:

O631

周奋国，周涛，何兴权，刘大军，段潜. 烷氧基苯基取代硫代双烯镍配合物近红外吸收材料的制备和表征[J]. 兵工学报, 2009, 30(9): 1227-1231.

ZHOU Fen-guo, ZHOU Tao, HE Xing-quan,LIU Da-jun, DUAN Qian. Preparation and Characterization of Near Infrared Absorbing Material Containing Dithiolene MetalComplexes Substituted by Alkoxyphenyl[J]. Acta Armamentarii, 2009, 30(9): 1227-1231.

参考文献

[1] Havens T G, Kerko D J, Morrell J A. classes for laser protec?tion： US, 5540745[P]. 1996-07-30.
[2] 关敏.激光防护玻璃[D].北京:中国建筑材料科学院，2004. uUAIN Min. Research of laser protection glass[DJ. Beijing： China Building Materials Academy, 2004. (in Chinese)
[3] Sallavanti R A，Lubianetsky M J. Laser-attenuative optical filter： US, 5271872[P]. 1993-10-21.
[4] Rosania R A, Gellner O. Near infrared electromagnetic radiation absorbing composition and method： US, 6794431 [P]. 2004-09- 24.
[5] Fabian J，Nakazumi H, Matsuoka M. Near - infrared absorbing dye[J]. Chemical Reviews, 1992, 92(6) ： 1197 — 1226.
[6] 孙成才，霍冀川,雷永林,等.近红外吸收功能菁染料的研究进展[J].材料导报,2006，20(8):48-51.
SUN Cheng-cai, HUO Ji-chuan, LEI Yong-Ii, et al. The ad?vance of studv on the near-intrared absorbing cyamne ayes [ J ]. Materials Review, 2006, 20(8) :48 — 51. (in Chinese)
[7] Yao K，Koike M, Suzuki Y, et al. Near infrared absorbing film, and multi-layered panel comprising the film： US, 6255031 [P]. 2001-07-01.
[8] 樊能廷.有机合成事典[M].北京：北京理工大学出版社， 2002:275-275.
FAN Neng-ting. Organic syntnetic dictionary[M]. Beijing： Bei?jing Institute of Technology Press, 2002： 275 一 275. (in Chi?nese)
[9] Celal Tüzün, Michael Ogliaruso, Ernest I Becker. 4，4'-bis (dimethylamino) benzyl [ EB/OL] . New York： John Wiley & Sons Inc, 1973. http： // www. orgsynth. org/orgsyn/orgsyn/ prepContent.asp? prep = cv5p0111.
[10] 伍林，易德莲，秦晓蓉，等.萘与草酰氯反应机理的探讨[J]. 武汉科技大学学报：自然科学版，2005,28(2)： 166 - 168.
WU Lin, YI De-lian, QIN Xiao-run, et al. Reaction mechanism of naphthalene with oxalyl chlonde[J] ? Journal of Wuhan Uni?versity of Science and Technology： Natural Science Edition, 2005,28(2):166-168. (in Chinese)
[11] 伍林，王艳，易德莲，等.苯与草酰氯反应机理的探讨[J]. 武汉科技大学学报：自然科学版，2005,28(3) :247 - 248.
Wu Lin, WANG Yan, YI De-lian, et al. Reaction mechanism of benzene witn oxalyl chlonde[J]. Journal ol Wuhan University of Science and Technology* Natural Science Edition, 2005, 28(3) ：247 — 248. (in Chinese)