黑索今含量对BAMO-AMMO基推进剂力学性能的影响

doi:10.3969/j.issn.1000-1093.2014.06.012

兵工学报 ›› 2014, Vol. 35 ›› Issue (6): 828-833.doi: 10.3969/j.issn.1000-1093.2014.06.012

黑索今含量对BAMO-AMMO基推进剂力学性能的影响

宋秀铎，郑伟，裴江峰，张军，王江宁，赵凤起

（西安近代化学研究所燃烧与爆炸技术重点实验室，陕西西安 710065）

收稿日期:2013-07-07 修回日期:2013-07-07 上线日期:2014-07-24
作者简介:宋秀铎(1978—)，男，高级工程师
基金资助:
总装备部“十二五”预先研究项目（62201070204）

Effect of RDX Content on Mechanical Properties of BAMO-AMMO Base Propellants

SONG Xiu-duo, ZHENG Wei, PEI Jiang-feng, ZHANG Jun, WANG Jiang-ning, ZHAO Feng-qi

(Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute,

Received:2013-07-07 Revised:2013-07-07 Online:2014-07-24

摘要/Abstract

摘要： 采用单轴拉伸实验考察了不同含量黑索今（RDX）固体填料对BAMO（聚双叠氮甲基-氧杂环丁烷）-AMMO（聚叠氮甲基-甲基氧杂环丁烷）基推进剂的拉伸力学性能影响。实验结果表明，随着RDX含量的增加，推进剂拉伸强度增加，延伸率减小，在含量为75%~85%时呈现平台效应。采用动态热机械分析（DMA）考察了不同固体填料含量BAMO-AMMO基推进剂的动态力学性能，分析了固体填料含量影响的机理。DMA分析结果表明，推进剂的玻璃化转变温度随RDX含量的变化规律与延生率变化规律一致，RDX含量增加，延伸率增大，玻璃化转变温度升高，损耗角正切值增大。

关键词: 兵器科学与技术, 固体推进剂, BAMOAMMO基推进剂, 力学性能, 动态热机械分析

Abstract: The mechanical properties of BAMO-AMMO base propellants with various amounts of RDX are characterized by using monaxial tensile test. The results show that the tensile stress of BAMO-AMMO base propellants increases and the tensile elongation decreases when the RDX content increases from 70% to 90%, but the change from 75% to 85% is inconspicuous. The effect of the RDX content on mechanical properties of BAMO-AMMO base propellants is analyzed by dynamic mechanical analyzer(DMA).The analysis result of DMA shows that the change rule of glass-transition temperature with RDX content is the same as that of tensile elongation. The elongation increases, the glass-transition temperature rises and the loss tangent (tan δ) enlarges with the increase in RDX content.

Key words: ordnance science and technology, solid propellant, BAMO-AMMO base propellant, mechanical property, dynamic thermomechanic analysis

中图分类号:

TG156

宋秀铎，郑伟，裴江峰，张军，王江宁，赵凤起. 黑索今含量对BAMO-AMMO基推进剂力学性能的影响[J]. 兵工学报, 2014, 35(6): 828-833.

SONG Xiu-duo, ZHENG Wei, PEI Jiang-feng, ZHANG Jun, WANG Jiang-ning, ZHAO Feng-qi. Effect of RDX Content on Mechanical Properties of BAMO-AMMO Base Propellants[J]. Acta Armamentarii, 2014, 35(6): 828-833.

参考文献

［1］沙恒. 国外双叠氮甲基氧杂环丁烷的应用研究[J]. 固体火箭技术, 1998,21(1)：39-42.
SHA Heng，The advance on application of diazidomethyl oxetane in America[J]. Journal of Solid Rocket Technology,1998,21(1)：39-42. (in Chinese)
[2］ Wadle R B. Method of producing thermoplastic elastomers having alternate crystalline structure for use as binders in high-energy compositions: US, 5516854[P］. 1996-05-14.
[3］ Hamiton R S, Wardle R B. A fully recyclable oxetane TPE rocket propellant[C]∥Proceedings of the 30th ICT International Annual. Conference. Karisruhe: ICT,1999: 4011-4016.
[4］卢先明，甘孝贤. 3,3-双迭氮甲基氧丁环聚合物的合成与性能[J].火炸药学报,2004,27(3):49-52.
LU Xian-ming, GAN Xiao-xian. Synthesis and properties of 3,3-diazidomethyloxetane and its polymer[J]. Chinese Journal of Explosives ＆ Propekkants,2004,27(3):49-52.(in Chinese)
[5］李娜,甘孝贤. 3-叠氮甲基-3-甲基氧丁环的合成[J]. 火炸药学报, 2005, 28(3):57-59．
LI Na, GAN Xiao-xian. Synthesis of 3-azidomethyl-3- methyloxetane[J]. Chinese Journal of Explosives ＆ Propekkants, 2005,28(3): 57-59. (in Chinese)
[6］甘孝贤，李娜，卢先明,等. BAMO-AMMO基ETPE的合成与性

能[J]. 火炸药学报, 2008, 31(2):81-85．
GAN Xiao-xian, LI Na, LU Xian-ming,et al. Synthesis and properties of ETPE based on BAMO-AMMO[J]. Chinese Journal of Explosives ＆ Propekkants,2008,31(2):81-85. (in Chinese)
[7］ Warren R C. Transition and relaxation in plasticized nitrocellulose [J]. Polymer, 1988, 29: 919-923.
[8］范夕萍, 刘子如, 孙莉霞, 等. NEPE-5固体推进剂物理老化的动态力学性能[J].含能材料, 2002, 10(3): 132-135.
FAN Xi-ping, LIU Zi-ru, SUN Li-xia, et al. Dynamic properties of aged NEPE-5[J]. Energetic Materials,2002, 10(3): 132-135. (in Chinese)
[9］姚楠，刘子如，王江宁，等. RDX含量对改性双基推进剂动态力学性能的影响[J]. 推进技术, 2008, 29(4):498-501.
YAO Nan, LIU Zi-ru, WANG Jiang-ning, et al. Effect of RDX content on dynamic mechanical properties of modified double-base propellants[J]. Journal of Propulsion Technology, 2008, 29(4): 498-501. (in Chinese)
[10］姚楠，刘子如，王江宁,等.RDX含量对改性双基推进剂动态力学性能的影响[J]. 推进技术, 2008, 29(5): 637-640.
YAO Nan, LIU Zi-ru,WANG Jiang-ning, et al. Effect of RDX content on dynamic mechanical properties of modified double-base propellants[J]. Journal of Propulsion Technology, 2008, 29(5): 637-640. (in Chinese)
[11］梁伯润. 高分子物理学[M].北京：中国纺织工业出版社，2000.
LIANG Bo-run. Polymer physics[M].Beijing: China Textile Industry Press,2000. (in Chinese)

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黑索今含量对BAMO-AMMO基推进剂力学性能的影响

Effect of RDX Content on Mechanical Properties of BAMO-AMMO Base Propellants

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